{"title":"从煤气化炉渣中提取多孔碳作为锂/钠离子电池的碳负极材料","authors":"Jingwen Huang, Haiqiang Bai, Jinghui Yang, Qingwen Ye, Xuanpan Gao, Yunhua Xu","doi":"10.1134/S0036024425701365","DOIUrl":null,"url":null,"abstract":"<p>As a fundamental technology for the efficient and environmentally friendly utilization of coal, the process of coal gasification inevitably generates a substantial amount of waste in the form of coal gasification slag. In this study, we utilized coal gasification slag as a raw material to extract carbon sources, employing potassium hydroxide (KOH) as an activator to prepare porous carbon. The electrochemical performance of this porous carbon was investigated in lithium/sodium ion batteries. When the ratio of KOH to residual carbon is 3 : 1, the resulting material demonstrates excellent lithium storage performance as an anode, achieving a reversible specific capacity of 452.83 mA h g<sup>–1</sup> at a current rate of 0.1 C. Furthermore, after undergoing 100 cycles at a current density of 0.5 C, the capacity remains stable at 272.64 mA h g<sup>–1</sup>. Conversely, when adjusting the KOH to carbon ratio to 1 : 1, optimal sodium storage performance is observed; specifically, the initial specific discharge capacity reaches 165.56 mA h g<sup>–1</sup> at a current density of 1 A g<sup>–1</sup>. These results indicate that carbon residue derived from coal gasification holds significant potential as an anode material in alkali metal ion batteries.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 8","pages":"1954 - 1962"},"PeriodicalIF":0.8000,"publicationDate":"2025-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Porous Carbon Obtained from Coal Gasification Slag Serves As a Carbon Anode Material for Lithium/Sodium Ion Batteries\",\"authors\":\"Jingwen Huang, Haiqiang Bai, Jinghui Yang, Qingwen Ye, Xuanpan Gao, Yunhua Xu\",\"doi\":\"10.1134/S0036024425701365\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>As a fundamental technology for the efficient and environmentally friendly utilization of coal, the process of coal gasification inevitably generates a substantial amount of waste in the form of coal gasification slag. In this study, we utilized coal gasification slag as a raw material to extract carbon sources, employing potassium hydroxide (KOH) as an activator to prepare porous carbon. The electrochemical performance of this porous carbon was investigated in lithium/sodium ion batteries. When the ratio of KOH to residual carbon is 3 : 1, the resulting material demonstrates excellent lithium storage performance as an anode, achieving a reversible specific capacity of 452.83 mA h g<sup>–1</sup> at a current rate of 0.1 C. Furthermore, after undergoing 100 cycles at a current density of 0.5 C, the capacity remains stable at 272.64 mA h g<sup>–1</sup>. Conversely, when adjusting the KOH to carbon ratio to 1 : 1, optimal sodium storage performance is observed; specifically, the initial specific discharge capacity reaches 165.56 mA h g<sup>–1</sup> at a current density of 1 A g<sup>–1</sup>. These results indicate that carbon residue derived from coal gasification holds significant potential as an anode material in alkali metal ion batteries.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"99 8\",\"pages\":\"1954 - 1962\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-08-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024425701365\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024425701365","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
煤气化作为煤炭高效、环保利用的基础技术,在气化过程中不可避免地产生大量的煤气化渣。本研究以煤气化渣为原料提取碳源,以氢氧化钾(KOH)为活化剂制备多孔碳。研究了多孔碳在锂/钠离子电池中的电化学性能。当KOH与残碳的比例为3:1时,该材料作为阳极具有优异的锂存储性能,在0.1 C的电流速率下实现了452.83 mA h g-1的可逆比容量,并且在0.5 C的电流密度下进行100次循环后,容量保持稳定在272.64 mA h g-1。相反,当KOH与碳的比例为1:1时,钠的储存性能最佳;在电流密度为1 a g-1时,初始比放电容量达到165.56 mA h g-1。这些结果表明,煤气化产生的碳渣作为碱金属离子电池的负极材料具有很大的潜力。
Porous Carbon Obtained from Coal Gasification Slag Serves As a Carbon Anode Material for Lithium/Sodium Ion Batteries
As a fundamental technology for the efficient and environmentally friendly utilization of coal, the process of coal gasification inevitably generates a substantial amount of waste in the form of coal gasification slag. In this study, we utilized coal gasification slag as a raw material to extract carbon sources, employing potassium hydroxide (KOH) as an activator to prepare porous carbon. The electrochemical performance of this porous carbon was investigated in lithium/sodium ion batteries. When the ratio of KOH to residual carbon is 3 : 1, the resulting material demonstrates excellent lithium storage performance as an anode, achieving a reversible specific capacity of 452.83 mA h g–1 at a current rate of 0.1 C. Furthermore, after undergoing 100 cycles at a current density of 0.5 C, the capacity remains stable at 272.64 mA h g–1. Conversely, when adjusting the KOH to carbon ratio to 1 : 1, optimal sodium storage performance is observed; specifically, the initial specific discharge capacity reaches 165.56 mA h g–1 at a current density of 1 A g–1. These results indicate that carbon residue derived from coal gasification holds significant potential as an anode material in alkali metal ion batteries.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.