四氟硼酸铜与双（2-吡啶基）-t-丁基膦配合物

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-06-02 DOI:10.1134/S0022476625050087

A. Yu. Baranov, I. Yu. Bagryanskaya, A. V. Artem’ev

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引用次数: 0

摘要

双（2-吡啶基）-t-丁基膦(L)与[Cu(MeCN)4]BF4在MeCN或CH2Cl2中反应形成双核配合物[Cu2L2](BF4)2(1)和[Cu2L2(MeCN)2](BF4)2(2)。在这两种配合物中，配体L充当P，N,N '桥接体，以头对尾的方式容纳两个Cu原子。在1的[Cu2L2]2+阳离子中，观察到Cu⋯Cu接触为2.756 Å，而在2的两个独立阳离子中，相似的距离为3.145-3.257 Å。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Copper(I) Tetrafluoroborate Complexes with bis(2-pyridyl)-t-Butylphosphine

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Copper(I) Tetrafluoroborate Complexes with bis(2-pyridyl)-t-Butylphosphine

The reaction of bis(2-pyridyl)-t-butylphosphine (L) with [Cu(MeCN)₄]BF₄ in MeCN or CH₂Cl₂ results in the formation of dinuclear complexes [Cu₂L₂](BF₄)₂ (1) and [Cu₂L₂(MeCN)₂](BF₄)₂ (2), respectively. In the both complexes, the ligands L act as P,N,N’-bridging ones, holding two Cu atoms in a head-to-tail manner. In the [Cu₂L₂]²⁺ cations of 1, the Cu⋯Cu contact of 2.756 Å is observed, while the similar distances in two independent cations of 2 are 3.145-3.257 Å.

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.