苯甲酸钴- 1,4-二氮杂-1,3-丁二烯三核配合物Mes-DAD的合成及结构分析

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-07-01 DOI:10.1134/S002247662506006X

V. A. Bushuev, D. S. Yambulatov, S. A. Nikolaevskii, N. V. Gogoleva, M. A. Kiskin, I. L. Eremenko

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引用次数: 0

摘要

通过乙酸钴（II）、苯甲酸（Hbz）和N，N ' -双（2,4,6-三甲基苯基）-1,4-二氮杂-1,3-丁二烯（Mes-DAD）在无水乙腈中相互作用得到分子三核钴（II）配合物[Co3(bz)6(Mes-DAD)2]·2MeCN (I)。I的晶体结构由单晶x射线衍射（CCDC No. 2423405）确定：苯甲酸阴离子作为桥，形成线性金属核，1,4-二氮-1,3-丁二烯配体与末端钴原子螯合。通过粉末x射线衍射分析证实了I的相纯度。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Analysis of the Structure of a Trinuclear Complex of Cobalt(II) Benzoate with 1,4-Diaza-1,3-Butadiene Ligand Mes-DAD

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Synthesis and Analysis of the Structure of a Trinuclear Complex of Cobalt(II) Benzoate with 1,4-Diaza-1,3-Butadiene Ligand Mes-DAD

Molecular trinuclear cobalt(II) complex [Co₃(bz)₆(Mes-DAD)₂]·2MeCN (I) is obtained by the interaction of cobalt(II) acetate, benzoic acid (Hbz), and N,N′-bis(2,4,6-trimethylphenyl)-1,4-diaza-1,3-butadiene (Mes-DAD) in absolute acetonitrile. The crystal structure of I is determined by single crystal X-ray diffraction (CCDC No. 2423405): benzoate anions act as bridges forming a linear metal core, 1,4-diaza-1,3-butadiene ligands are chelated to terminal cobalt atoms. The phase purity of I is confirmed by the powder X-ray diffraction analysis.

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.