{"title":"白菜状NiCo2O4/rGO纳米复合材料:提高下一代超级电容器的电容和功率密度","authors":"Bandana Jadawn, Pukhrambam Dipak, Rajendra Kumar Tiwari, Radha Tomar","doi":"10.3103/S1068335624602085","DOIUrl":null,"url":null,"abstract":"<p>In the present work, NiCo<sub>2</sub>O<sub>4</sub> and NiCo<sub>2</sub>O<sub>4</sub>/rGO nanocomposites were synthesized by using hydrothermal method. Thermogravimetric analysis (TGA) reveals that NiCo<sub>2</sub>O<sub>4</sub>/rGO was more stable as compared to NiCo<sub>2</sub>O<sub>4</sub>. Electrochemical studies reveal that the NiCo<sub>2</sub>O<sub>4</sub>/rGO exhibits high specific capacitance of 1960 F/g in comparison with NiCo<sub>2</sub>O<sub>4</sub> of 870 F/g. NiCo<sub>2</sub>O<sub>4</sub>/rGO has energy density of 300 W h/kg at low power density and ultra high power density of 18.74 kW/kg at low energy density. Incorporation of reduced graphene oxide increases the specific capacitance, energy density and power density of the electrode material. The SEM micrographs reveal the formation of cabbage-like structure of the nanocomposite. These results of NiCo<sub>2</sub>O<sub>4</sub>/rGO have drawn increasing attention as the latter is a promising electrode material for high performance supercapacitors.</p>","PeriodicalId":503,"journal":{"name":"Bulletin of the Lebedev Physics Institute","volume":"52 6","pages":"265 - 273"},"PeriodicalIF":0.7000,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cabbage-Like NiCo2O4/rGO Nanocomposites: Boosting Capacitance and Power Density for Next-Generation Supercapacitors\",\"authors\":\"Bandana Jadawn, Pukhrambam Dipak, Rajendra Kumar Tiwari, Radha Tomar\",\"doi\":\"10.3103/S1068335624602085\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In the present work, NiCo<sub>2</sub>O<sub>4</sub> and NiCo<sub>2</sub>O<sub>4</sub>/rGO nanocomposites were synthesized by using hydrothermal method. Thermogravimetric analysis (TGA) reveals that NiCo<sub>2</sub>O<sub>4</sub>/rGO was more stable as compared to NiCo<sub>2</sub>O<sub>4</sub>. Electrochemical studies reveal that the NiCo<sub>2</sub>O<sub>4</sub>/rGO exhibits high specific capacitance of 1960 F/g in comparison with NiCo<sub>2</sub>O<sub>4</sub> of 870 F/g. NiCo<sub>2</sub>O<sub>4</sub>/rGO has energy density of 300 W h/kg at low power density and ultra high power density of 18.74 kW/kg at low energy density. Incorporation of reduced graphene oxide increases the specific capacitance, energy density and power density of the electrode material. The SEM micrographs reveal the formation of cabbage-like structure of the nanocomposite. These results of NiCo<sub>2</sub>O<sub>4</sub>/rGO have drawn increasing attention as the latter is a promising electrode material for high performance supercapacitors.</p>\",\"PeriodicalId\":503,\"journal\":{\"name\":\"Bulletin of the Lebedev Physics Institute\",\"volume\":\"52 6\",\"pages\":\"265 - 273\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2025-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of the Lebedev Physics Institute\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S1068335624602085\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of the Lebedev Physics Institute","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.3103/S1068335624602085","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
采用水热法制备了NiCo2O4和NiCo2O4/还原氧化石墨烯纳米复合材料。热重分析(TGA)表明NiCo2O4/rGO比NiCo2O4更稳定。电化学研究表明,NiCo2O4/rGO的比电容为1960 F/g, NiCo2O4的比电容为870 F/g。NiCo2O4/rGO在低功率密度下具有300 W h/kg的能量密度,在低能量密度下具有18.74 kW/kg的超高功率密度。加入还原氧化石墨烯增加了电极材料的比电容、能量密度和功率密度。SEM显微图显示了纳米复合材料的白菜状结构的形成。由于NiCo2O4/rGO是一种很有前途的高性能超级电容器电极材料,这些研究结果引起了越来越多的关注。
Cabbage-Like NiCo2O4/rGO Nanocomposites: Boosting Capacitance and Power Density for Next-Generation Supercapacitors
In the present work, NiCo2O4 and NiCo2O4/rGO nanocomposites were synthesized by using hydrothermal method. Thermogravimetric analysis (TGA) reveals that NiCo2O4/rGO was more stable as compared to NiCo2O4. Electrochemical studies reveal that the NiCo2O4/rGO exhibits high specific capacitance of 1960 F/g in comparison with NiCo2O4 of 870 F/g. NiCo2O4/rGO has energy density of 300 W h/kg at low power density and ultra high power density of 18.74 kW/kg at low energy density. Incorporation of reduced graphene oxide increases the specific capacitance, energy density and power density of the electrode material. The SEM micrographs reveal the formation of cabbage-like structure of the nanocomposite. These results of NiCo2O4/rGO have drawn increasing attention as the latter is a promising electrode material for high performance supercapacitors.
期刊介绍:
Bulletin of the Lebedev Physics Institute is an international peer reviewed journal that publishes results of new original experimental and theoretical studies on all topics of physics: theoretical physics; atomic and molecular physics; nuclear physics; optics; lasers; condensed matter; physics of solids; biophysics, and others.