V. V. Zamalyutin, E. V. Okuneva, S. S. Moskvichev, V. R. Flid
{"title":"降冰片烯系列碳环化合物的非均相加氢和异构化研究进展","authors":"V. V. Zamalyutin, E. V. Okuneva, S. S. Moskvichev, V. R. Flid","doi":"10.1134/S2070050425700059","DOIUrl":null,"url":null,"abstract":"<p>The main laws and routes of the liquid-phase hydrogenation and isomerization of carbocyclic alkenes and dienes of the norbornene series in the presence of heterogeneous catalysts were systematized, and the reaction mechanisms were discussed. The reaction products were identified and the material balance was studied. Conditions for the hydrogenation and isomerization of the compounds were selected such as to provide the preservation of the norbornane framework. The reactivity of multiple bonds in norbornenes was assessed by experimental and quantum chemical methods. Adequate kinetic models of the processes in terms of the Langmuir–Hinshelwood approach and in the representation of multiple adsorption of substrates on a single active site were developed.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"17 2","pages":"133 - 156"},"PeriodicalIF":1.3000,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Heterogeneous Hydrogenation and Isomerization of Carbocyclic Compounds of the Norbornene Series: A Review\",\"authors\":\"V. V. Zamalyutin, E. V. Okuneva, S. S. Moskvichev, V. R. Flid\",\"doi\":\"10.1134/S2070050425700059\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The main laws and routes of the liquid-phase hydrogenation and isomerization of carbocyclic alkenes and dienes of the norbornene series in the presence of heterogeneous catalysts were systematized, and the reaction mechanisms were discussed. The reaction products were identified and the material balance was studied. Conditions for the hydrogenation and isomerization of the compounds were selected such as to provide the preservation of the norbornane framework. The reactivity of multiple bonds in norbornenes was assessed by experimental and quantum chemical methods. Adequate kinetic models of the processes in terms of the Langmuir–Hinshelwood approach and in the representation of multiple adsorption of substrates on a single active site were developed.</p>\",\"PeriodicalId\":507,\"journal\":{\"name\":\"Catalysis in Industry\",\"volume\":\"17 2\",\"pages\":\"133 - 156\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2025-06-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis in Industry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070050425700059\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis in Industry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2070050425700059","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Heterogeneous Hydrogenation and Isomerization of Carbocyclic Compounds of the Norbornene Series: A Review
The main laws and routes of the liquid-phase hydrogenation and isomerization of carbocyclic alkenes and dienes of the norbornene series in the presence of heterogeneous catalysts were systematized, and the reaction mechanisms were discussed. The reaction products were identified and the material balance was studied. Conditions for the hydrogenation and isomerization of the compounds were selected such as to provide the preservation of the norbornane framework. The reactivity of multiple bonds in norbornenes was assessed by experimental and quantum chemical methods. Adequate kinetic models of the processes in terms of the Langmuir–Hinshelwood approach and in the representation of multiple adsorption of substrates on a single active site were developed.
期刊介绍：
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
