坦桑尼亚东南部Mandawa盆地Bajocian-Bathonian series (Mtumbei组)烃源岩潜力

IF 1.3 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
John William Gama, Emily Barnabas Kiswaka
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引用次数: 0

摘要

在过去的几十年里,坦桑尼亚海岸盆地的中侏罗世沉积物在区域古地理尺度上引起了人们的关注。这些沉积物,包括厚厚的黑色页岩,是在冈瓦纳超大陆分裂引发的广泛海侵之后沉积的。前人研究表明,这些页岩具有良好至极好的烃源潜力,是很有潜力的区域烃源岩。然而,没有详细的地球化学研究评估它们在曼达瓦盆地。本研究通过对两口井的岩屑样品进行地球化学评价,以:(1)约束曼达瓦盆地Bajocian-Bathonian黑色页岩的有机质丰度、类型和质量,(2)重建巴约阶—巴bathonian黑色页岩的热演化和沉积条件。通过总有机碳(TOC)分析测定有机质丰富度,通过程序热解评价有机质质量和热成熟度。古氧化还原条件由伽马射线测井数据得出的Th/U比值确定。地球化学数据显示,该区有机质含量普遍偏低,且存在空间差异。分析的TOC含量沿地层波动,取值范围为0.13 ~ 3.59 wt%,平均值为0.92 wt%。而干酪根产率(S2)和氢指数(HI)普遍较低;S2范围为0 ~ 1.95 (mg HC/g),平均值为0.29 (mg HC/g); HI范围为0 ~ 92 (mg HC/g TOC),平均值为24 (mg HC/g TOC)。有机质主要由III型(易气型)至IV型(惰性型)组成,经历了从边缘成熟到过成熟的广泛热蚀变。对比岩屑样品的TOC、Th/U和沉积物组成数据(碎屑和碳酸盐)表明,在亚氧条件下有机质有幕式沉积。这主要受海平面波动、构造和碎屑稀释作用的控制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Source rock potential of the Bajocian-Bathonian succession (Mtumbei Formation) in the Mandawa Basin, SE Tanzania

Over the past few decades, Middle Jurassic sediments in the Tanzanian Coastal Basin have gained attention on a regional palaeogeographical scale. These sediments, including thick black shales, were deposited following a widespread marine transgression initiated by the breakup of Gondwana supercontinent. Previous studies indicate that these shales possess good to excellent source potential, making them promising regional source rocks. However, no detailed geochemical studies have assessed them in the Mandawa Basin. In this study, geochemical assessment was caried out on cutting samples from two wells to: (i) constrain organic matter richness, type, quality, and: (ii) reconstruct thermal evolution and depositional conditions of the Bajocian-Bathonian black shales in the Mandawa Basin. Organic matter richness was measured using Total Organic Carbon (TOC) analysis, while the quality and thermal maturity of the organic matter were assessed through programmed pyrolysis. Paleo-redox conditions were determined from Th/U ratios derived from Spectra Gamma Ray Logs data. Geochemical data reveal that organic matter content (TOC) is generally low and varies spatially. The analysed TOC content fluctuates along stratigraphy with values ranging from 0.13 to 3.59 wt% with an average of 0.92 wt%. Whereas, Kerogen yield (S2) and Hydrogen Index (HI) are generally low; S2 and HI ranges from 0 to 1.95 (mg HC/g) with an average of 0.29 (mg HC/g), and 0‒92 (mg HC/g TOC) with an average of 24 (mg HC/g TOC), respectively. Organic matter is mainly composed of types III (gas prone) to IV (inert) that have been subjected to wide range of thermal alteration ranging from marginally mature to over mature. Comparison of TOC, Th/U and sediment composition data (clastics and carbonates) derived from cuttings samples suggests episodic deposition of organic matter under sub-oxic conditions. These were mainly controlled by fluctuation in sea level, tectonics and clastic dilution.

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来源期刊
Acta Geochimica
Acta Geochimica GEOCHEMISTRY & GEOPHYSICS-
CiteScore
2.80
自引率
6.20%
发文量
1134
期刊介绍: Acta Geochimica serves as the international forum for essential research on geochemistry, the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth‘s crust, its oceans and the entire Solar System, as well as a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. The journal focuses on, but is not limited to the following aspects: • Cosmochemistry • Mantle Geochemistry • Ore-deposit Geochemistry • Organic Geochemistry • Environmental Geochemistry • Computational Geochemistry • Isotope Geochemistry • NanoGeochemistry All research articles published in this journal have undergone rigorous peer review. In addition to original research articles, Acta Geochimica publishes reviews and short communications, aiming to rapidly disseminate the research results of timely interest, and comprehensive reviews of emerging topics in all the areas of geochemistry.
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