改进固定床催化重整过程数学模型

IF 1.3 Q4 ENGINEERING, CHEMICAL
I. V. Pchelintseva, E. N. Ivashkina, E. S. Chernyakova, D. B. Tazhmulikov, V. A. Chyuzlov
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引用次数: 0

摘要

本文建立了一个数学模型,充分描述了催化重整过程,这是俄罗斯和国外获得发动机燃料高辛烷值组分的主要工业技术。指出了扩大现有的汽油系列烃类转化方案的必要性,以创建一个改造各种来源原料(热破坏过程的汽油馏分、加氢裂化石脑油、凝析油)的模型。根据气相色谱的实验研究结果,以及热力学参数的计算,编制了一个改进的形式化反应方案,以考虑涉及不饱和烃的反应。建立了膨胀汽油馏分重整过程的动力学模型。为了描述基于烃类转化形式化方案的动力学模型,采用了矩阵法,使模型对原料组成具有更大的灵活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Improving the Mathematical Model of the Catalytic Reforming Process with a Fixed Catalyst Bed

Improving the Mathematical Model of the Catalytic Reforming Process with a Fixed Catalyst Bed

A mathematical model that adequately describes the process of catalytic reforming—the main industrial technology for obtaining high-octane components of motor fuels in Russia and abroad is presented. The necessity of expanding the existing scheme of transformations of hydrocarbons of the gasoline series to create a model of reforming feedstocks of various origins (gasoline fractions of thermal destructive processes, hydrocracking naphtha, gas condensate) is shown. Based on the results of experimental studies using gas chromatography, as well as the calculations of thermodynamic parameters, an improved formalized reaction scheme has been compiled to take into account into account reactions involving unsaturated hydrocarbons. A kinetic model of the reforming process of the expanded gasoline fraction has been compiled. To describe the kinetic model based on the formalized scheme of hydrocarbon transformations, a matrix method was used, which makes the model more flexible to the composition of the feedstock.

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来源期刊
Catalysis in Industry
Catalysis in Industry ENGINEERING, CHEMICAL-
CiteScore
1.30
自引率
14.30%
发文量
21
期刊介绍: The journal covers the following topical areas: Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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