I. V. Pchelintseva, E. N. Ivashkina, E. S. Chernyakova, D. B. Tazhmulikov, V. A. Chyuzlov
{"title":"改进固定床催化重整过程数学模型","authors":"I. V. Pchelintseva, E. N. Ivashkina, E. S. Chernyakova, D. B. Tazhmulikov, V. A. Chyuzlov","doi":"10.1134/S2070050425700072","DOIUrl":null,"url":null,"abstract":"<p>A mathematical model that adequately describes the process of catalytic reforming—the main industrial technology for obtaining high-octane components of motor fuels in Russia and abroad is presented. The necessity of expanding the existing scheme of transformations of hydrocarbons of the gasoline series to create a model of reforming feedstocks of various origins (gasoline fractions of thermal destructive processes, hydrocracking naphtha, gas condensate) is shown. Based on the results of experimental studies using gas chromatography, as well as the calculations of thermodynamic parameters, an improved formalized reaction scheme has been compiled to take into account into account reactions involving unsaturated hydrocarbons. A kinetic model of the reforming process of the expanded gasoline fraction has been compiled. To describe the kinetic model based on the formalized scheme of hydrocarbon transformations, a matrix method was used, which makes the model more flexible to the composition of the feedstock.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"17 2","pages":"162 - 176"},"PeriodicalIF":1.3000,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improving the Mathematical Model of the Catalytic Reforming Process with a Fixed Catalyst Bed\",\"authors\":\"I. V. Pchelintseva, E. N. Ivashkina, E. S. Chernyakova, D. B. Tazhmulikov, V. A. Chyuzlov\",\"doi\":\"10.1134/S2070050425700072\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A mathematical model that adequately describes the process of catalytic reforming—the main industrial technology for obtaining high-octane components of motor fuels in Russia and abroad is presented. The necessity of expanding the existing scheme of transformations of hydrocarbons of the gasoline series to create a model of reforming feedstocks of various origins (gasoline fractions of thermal destructive processes, hydrocracking naphtha, gas condensate) is shown. Based on the results of experimental studies using gas chromatography, as well as the calculations of thermodynamic parameters, an improved formalized reaction scheme has been compiled to take into account into account reactions involving unsaturated hydrocarbons. A kinetic model of the reforming process of the expanded gasoline fraction has been compiled. To describe the kinetic model based on the formalized scheme of hydrocarbon transformations, a matrix method was used, which makes the model more flexible to the composition of the feedstock.</p>\",\"PeriodicalId\":507,\"journal\":{\"name\":\"Catalysis in Industry\",\"volume\":\"17 2\",\"pages\":\"162 - 176\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2025-06-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis in Industry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070050425700072\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis in Industry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2070050425700072","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Improving the Mathematical Model of the Catalytic Reforming Process with a Fixed Catalyst Bed
A mathematical model that adequately describes the process of catalytic reforming—the main industrial technology for obtaining high-octane components of motor fuels in Russia and abroad is presented. The necessity of expanding the existing scheme of transformations of hydrocarbons of the gasoline series to create a model of reforming feedstocks of various origins (gasoline fractions of thermal destructive processes, hydrocracking naphtha, gas condensate) is shown. Based on the results of experimental studies using gas chromatography, as well as the calculations of thermodynamic parameters, an improved formalized reaction scheme has been compiled to take into account into account reactions involving unsaturated hydrocarbons. A kinetic model of the reforming process of the expanded gasoline fraction has been compiled. To describe the kinetic model based on the formalized scheme of hydrocarbon transformations, a matrix method was used, which makes the model more flexible to the composition of the feedstock.
期刊介绍:
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.