高低压聚乙烯与含镍纳米填料混合纳米复合材料性能研究

IF 0.3 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
G. G. Mamedova, N. I. Kurbanova, T. M. Gulieva, E. G. Iskenderova
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引用次数: 0

摘要

采用x射线相分析(XPA)、差热分析(DTA)和扫描电子显微镜(SEM)研究了以高密度聚乙烯和低密度聚乙烯为基体,添加细氧化镍的复合材料。细氧化镍的引入提高了复合材料的强度、变形性能和热氧化稳定性,这显然与含镍纳米颗粒与聚合物组分之间形成界面键有关。结果表明,高密度聚乙烯和低密度聚乙烯混合基纳米复合材料在添加细氧化镍的情况下,既可以用压制法加工,也可以用注塑和挤压法加工,从而扩大了其应用领域。少量的纳米填充剂被引入到聚合物中作为结构形成剂,即人工结晶核,这有助于在聚合物中形成精细的球状结构,其特征是所得到的纳米复合材料的物理力学和热性能得到改善。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

An Investigation of the Properties of Nanocomposites Based on a Mixture of High and Low Pressure Polyethylene with Nickel-Containing Nanofillers

An Investigation of the Properties of Nanocomposites Based on a Mixture of High and Low Pressure Polyethylene with Nickel-Containing Nanofillers

Composite materials based on a mixture of high-density and low-density polyethylenes, including additives of fine nickel oxide, were investigated using X-ray phase analysis (XPA), differential thermal analysis (DTA), and scanning electron microscopy (SEM). An improvement in the strength, deformation properties, and thermo-oxidative stability of the composites was revealed upon the introduction of fine nickel oxide, which is apparently associated with the formation of interfacial bonds between the nickel-containing nanoparticles and the components of the polymer composition. It was shown that nanocomposites based on a mixture of high-density and low-density polyethylenes, including additives of fine nickel oxide, can be processed by both pressing and methods of injection molding and extrusion, thereby expanding their fields of application. Small amounts of the nanofiller introduced into the polymer act as structure-forming agents, that is, artificial crystallization nuclei, which contributes to the formation of a fine spherulitic structure in the polymer, as characterized by the improved physical–mechanical and thermal properties of the resulting nanocomposite.

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来源期刊
Inorganic Materials: Applied Research
Inorganic Materials: Applied Research Engineering-Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
199
期刊介绍: Inorganic Materials: Applied Research  contains translations of research articles devoted to applied aspects of inorganic materials. Best articles are selected from four Russian periodicals: Materialovedenie, Perspektivnye Materialy, Fizika i Khimiya Obrabotki Materialov, and Voprosy Materialovedeniya  and translated into English. The journal reports recent achievements in materials science: physical and chemical bases of materials science; effects of synergism in composite materials; computer simulations; creation of new materials (including carbon-based materials and ceramics, semiconductors, superconductors, composite materials, polymers, materials for nuclear engineering, materials for aircraft and space engineering, materials for quantum electronics, materials for electronics and optoelectronics, materials for nuclear and thermonuclear power engineering, radiation-hardened materials, materials for use in medicine, etc.); analytical techniques; structure–property relationships; nanostructures and nanotechnologies; advanced technologies; use of hydrogen in structural materials; and economic and environmental issues. The journal also considers engineering issues of materials processing with plasma, high-gradient crystallization, laser technology, and ultrasonic technology. Currently the journal does not accept direct submissions, but submissions to one of the source journals is possible.
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