{"title":"温差引起的表面张力梯度使W-30Cu复合材料通过超快高温烧结实现了高密度化","authors":"Pengqi Chen , Chengyang Huang , Jiarui Su , Dang Xu , Hongyu Chen , Xinyuan Shen , Jigui Cheng","doi":"10.1016/j.jmrt.2025.09.171","DOIUrl":null,"url":null,"abstract":"<div><div>The fabrication of highly dense W-Cu composites using conventional powder metallurgy techniques remains challenging, due to the significant differences in physical properties between tungsten and copper. In this study, micron-sized tungsten powder and spherical copper powder were selected as raw materials to prepare W-30Cu composite powders. Sintering was performed using the ultra-fast sintering (UHS) technique at temperatures ranging from 1050 °C to 1200 °C with holding times of 1, 3, 5, and 10 min. The results reveal that the sample sintered at 1150 °C for 10 min exhibited the highest relative density of 95.4 % and thermal conductivity of 234.2 W m<sup>−1</sup> K<sup>−1</sup>. During the UHS process, the steep thermal gradient induced a surface tension gradient, which promoted the redistribution of the copper liquid phase and the rearrangement of tungsten particles. Compared to conventional tube furnace sintering under uniform temperature fields, this approach significantly enhanced densification and performance within a much shorter time. These findings suggest that the application of UHS provides a promising pathway for the fabrication of advanced composite materials.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"39 ","pages":"Pages 862-872"},"PeriodicalIF":6.6000,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Temperature difference-induced surface tension gradients enable high densification of W-30Cu composites via ultrafast high-temperature sintering\",\"authors\":\"Pengqi Chen , Chengyang Huang , Jiarui Su , Dang Xu , Hongyu Chen , Xinyuan Shen , Jigui Cheng\",\"doi\":\"10.1016/j.jmrt.2025.09.171\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The fabrication of highly dense W-Cu composites using conventional powder metallurgy techniques remains challenging, due to the significant differences in physical properties between tungsten and copper. In this study, micron-sized tungsten powder and spherical copper powder were selected as raw materials to prepare W-30Cu composite powders. Sintering was performed using the ultra-fast sintering (UHS) technique at temperatures ranging from 1050 °C to 1200 °C with holding times of 1, 3, 5, and 10 min. The results reveal that the sample sintered at 1150 °C for 10 min exhibited the highest relative density of 95.4 % and thermal conductivity of 234.2 W m<sup>−1</sup> K<sup>−1</sup>. During the UHS process, the steep thermal gradient induced a surface tension gradient, which promoted the redistribution of the copper liquid phase and the rearrangement of tungsten particles. Compared to conventional tube furnace sintering under uniform temperature fields, this approach significantly enhanced densification and performance within a much shorter time. These findings suggest that the application of UHS provides a promising pathway for the fabrication of advanced composite materials.</div></div>\",\"PeriodicalId\":54332,\"journal\":{\"name\":\"Journal of Materials Research and Technology-Jmr&t\",\"volume\":\"39 \",\"pages\":\"Pages 862-872\"},\"PeriodicalIF\":6.6000,\"publicationDate\":\"2025-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Research and Technology-Jmr&t\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2238785425024251\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Research and Technology-Jmr&t","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2238785425024251","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
由于钨和铜的物理性质存在显著差异,使用传统粉末冶金技术制备高密度W-Cu复合材料仍然具有挑战性。本研究以微米级钨粉和球形铜粉为原料,制备了W-30Cu复合粉末。烧结采用超快速烧结(UHS)技术,温度范围为1050°C至1200°C,保温时间为1、3、5和10分钟。结果表明,在1150℃下烧结10 min的样品相对密度最高,为95.4%,导热系数为234.2 W m−1 K−1。在UHS过程中,陡峭的热梯度引起表面张力梯度,促进了铜液相的重新分布和钨颗粒的重排。与均匀温度场下的传统管式炉烧结相比,该方法在更短的时间内显著提高了致密性和性能。这些发现表明,UHS的应用为先进复合材料的制造提供了一条有前途的途径。
Temperature difference-induced surface tension gradients enable high densification of W-30Cu composites via ultrafast high-temperature sintering
The fabrication of highly dense W-Cu composites using conventional powder metallurgy techniques remains challenging, due to the significant differences in physical properties between tungsten and copper. In this study, micron-sized tungsten powder and spherical copper powder were selected as raw materials to prepare W-30Cu composite powders. Sintering was performed using the ultra-fast sintering (UHS) technique at temperatures ranging from 1050 °C to 1200 °C with holding times of 1, 3, 5, and 10 min. The results reveal that the sample sintered at 1150 °C for 10 min exhibited the highest relative density of 95.4 % and thermal conductivity of 234.2 W m−1 K−1. During the UHS process, the steep thermal gradient induced a surface tension gradient, which promoted the redistribution of the copper liquid phase and the rearrangement of tungsten particles. Compared to conventional tube furnace sintering under uniform temperature fields, this approach significantly enhanced densification and performance within a much shorter time. These findings suggest that the application of UHS provides a promising pathway for the fabrication of advanced composite materials.
期刊介绍:
The Journal of Materials Research and Technology is a publication of ABM - Brazilian Metallurgical, Materials and Mining Association - and publishes four issues per year also with a free version online (www.jmrt.com.br). The journal provides an international medium for the publication of theoretical and experimental studies related to Metallurgy, Materials and Minerals research and technology. Appropriate submissions to the Journal of Materials Research and Technology should include scientific and/or engineering factors which affect processes and products in the Metallurgy, Materials and Mining areas.