Libo Deng , Huitian Du , Jing Sun , Hongli Xu , Zhuo Chen , Hangwen Qu , Guangfen Wei , Pingjian Wang , Zhuhui Qiao , Zhonghai Lin
{"title":"DebNet结合荧光光谱技术在多种农药残留快速分类中的应用","authors":"Libo Deng , Huitian Du , Jing Sun , Hongli Xu , Zhuo Chen , Hangwen Qu , Guangfen Wei , Pingjian Wang , Zhuhui Qiao , Zhonghai Lin","doi":"10.1016/j.chemolab.2025.105540","DOIUrl":null,"url":null,"abstract":"<div><div>The illegal use of pesticides has led to severe residual pollution, posing serious threats to both human health and the environment. This situation underscores the urgent need for rapid and highly accurate classification methods for multi-pesticide residue detection. Although fluorescence spectroscopy remains a mainstream technique in this field, its classification performance is often limited by spectral overlap and background noise. To address these challenges, this study proposes DebNet, a deep learning model based on one-dimensional fluorescence spectral data. DebNet integrates one-dimensional convolutional neural networks (1D-CNN), long short-term memory (LSTM) networks, and self-attention mechanisms to collaboratively mitigate spectral interference. Experimental results demonstrate that DebNet achieves a classification accuracy of 99.83 % on preprocessed data, with a training time of approximately 5 min. It enables fast and accurate classification of four high-risk pesticides, including cyromazine, captan, metolachlor and thiamethoxam. Overall, the proposed method offers a lightweight and effective solution for real-time monitoring of pesticide residues in agricultural environments. Its robustness under spectral overlap conditions makes it particularly suitable for on-site applications requiring rapid and accurate classification.</div></div>","PeriodicalId":9774,"journal":{"name":"Chemometrics and Intelligent Laboratory Systems","volume":"267 ","pages":"Article 105540"},"PeriodicalIF":3.8000,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Application of DebNet combined with fluorescence spectroscopy for rapid multi-pesticide residue classification\",\"authors\":\"Libo Deng , Huitian Du , Jing Sun , Hongli Xu , Zhuo Chen , Hangwen Qu , Guangfen Wei , Pingjian Wang , Zhuhui Qiao , Zhonghai Lin\",\"doi\":\"10.1016/j.chemolab.2025.105540\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The illegal use of pesticides has led to severe residual pollution, posing serious threats to both human health and the environment. This situation underscores the urgent need for rapid and highly accurate classification methods for multi-pesticide residue detection. Although fluorescence spectroscopy remains a mainstream technique in this field, its classification performance is often limited by spectral overlap and background noise. To address these challenges, this study proposes DebNet, a deep learning model based on one-dimensional fluorescence spectral data. DebNet integrates one-dimensional convolutional neural networks (1D-CNN), long short-term memory (LSTM) networks, and self-attention mechanisms to collaboratively mitigate spectral interference. Experimental results demonstrate that DebNet achieves a classification accuracy of 99.83 % on preprocessed data, with a training time of approximately 5 min. It enables fast and accurate classification of four high-risk pesticides, including cyromazine, captan, metolachlor and thiamethoxam. Overall, the proposed method offers a lightweight and effective solution for real-time monitoring of pesticide residues in agricultural environments. Its robustness under spectral overlap conditions makes it particularly suitable for on-site applications requiring rapid and accurate classification.</div></div>\",\"PeriodicalId\":9774,\"journal\":{\"name\":\"Chemometrics and Intelligent Laboratory Systems\",\"volume\":\"267 \",\"pages\":\"Article 105540\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-09-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemometrics and Intelligent Laboratory Systems\",\"FirstCategoryId\":\"94\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0169743925002254\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"AUTOMATION & CONTROL SYSTEMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemometrics and Intelligent Laboratory Systems","FirstCategoryId":"94","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169743925002254","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"AUTOMATION & CONTROL SYSTEMS","Score":null,"Total":0}
Application of DebNet combined with fluorescence spectroscopy for rapid multi-pesticide residue classification
The illegal use of pesticides has led to severe residual pollution, posing serious threats to both human health and the environment. This situation underscores the urgent need for rapid and highly accurate classification methods for multi-pesticide residue detection. Although fluorescence spectroscopy remains a mainstream technique in this field, its classification performance is often limited by spectral overlap and background noise. To address these challenges, this study proposes DebNet, a deep learning model based on one-dimensional fluorescence spectral data. DebNet integrates one-dimensional convolutional neural networks (1D-CNN), long short-term memory (LSTM) networks, and self-attention mechanisms to collaboratively mitigate spectral interference. Experimental results demonstrate that DebNet achieves a classification accuracy of 99.83 % on preprocessed data, with a training time of approximately 5 min. It enables fast and accurate classification of four high-risk pesticides, including cyromazine, captan, metolachlor and thiamethoxam. Overall, the proposed method offers a lightweight and effective solution for real-time monitoring of pesticide residues in agricultural environments. Its robustness under spectral overlap conditions makes it particularly suitable for on-site applications requiring rapid and accurate classification.
期刊介绍:
Chemometrics and Intelligent Laboratory Systems publishes original research papers, short communications, reviews, tutorials and Original Software Publications reporting on development of novel statistical, mathematical, or computer techniques in Chemistry and related disciplines.
Chemometrics is the chemical discipline that uses mathematical and statistical methods to design or select optimal procedures and experiments, and to provide maximum chemical information by analysing chemical data.
The journal deals with the following topics:
1) Development of new statistical, mathematical and chemometrical methods for Chemistry and related fields (Environmental Chemistry, Biochemistry, Toxicology, System Biology, -Omics, etc.)
2) Novel applications of chemometrics to all branches of Chemistry and related fields (typical domains of interest are: process data analysis, experimental design, data mining, signal processing, supervised modelling, decision making, robust statistics, mixture analysis, multivariate calibration etc.) Routine applications of established chemometrical techniques will not be considered.
3) Development of new software that provides novel tools or truly advances the use of chemometrical methods.
4) Well characterized data sets to test performance for the new methods and software.
The journal complies with International Committee of Medical Journal Editors'' Uniform requirements for manuscripts.