Jean C. Neto, Ayman Larek, Juan F. Miravet, Minoru Yamaji, Francisco Galindo
{"title":"通过聚合物网络工程展示白光发射的有机、透明和柔性薄膜:一种非染料中心策略","authors":"Jean C. Neto, Ayman Larek, Juan F. Miravet, Minoru Yamaji, Francisco Galindo","doi":"10.1002/adom.202501380","DOIUrl":null,"url":null,"abstract":"<p>White light-emitting (WLE) materials are often engineered by tailoring fluorescent dyes to generate balanced emission spectra. In such dye-focused methodologies, the matrix plays a minimal role beyond hosting the emitters. However, this strategy can be unpredictable due to the complexity of modifying dye photophysics with precision. In the work here presented, a matrix-driven approach to WLE is introduced, where the properties of the polymeric host are leveraged to regulate light emission. By adjusting the composition of the polymer network with variation in monomers and cross-linkers, it is possible to control the spatial arrangement and interaction of two dyes, enabling effective color mixing. The system employs readily available monomers, 2-hydroxyethyl methacrylate (HEMA) and poly(ethylene glycol) dimethacrylate (PEGDMA), along with two simple, synthetically accessible dyes: a pyridinium salt and a pyrylium derivative. The resulting hydrogel-based films emit white light with Commission Internationale de l'Éclairage (CIE) chromaticity coordinates at (0.30, 0.33) and a high photoluminescence quantum yield of 0.51. The films are highly transparent, flexible, and suitable for back-illumination, making them excellent candidates for integration into next-generation optoelectronic platforms, such as bendable lighting elements, transparent displays, and wearable light sources. This strategy highlights the untapped potential of polymer matrices in fine-tuning emissive behavior.</p>","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 27","pages":""},"PeriodicalIF":7.2000,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/adom.202501380","citationCount":"0","resultStr":"{\"title\":\"Organic, Transparent, and Flexible Films Exhibiting White-Light Emission via Polymer-Network Engineering: A Non-Dye-Centric Strategy\",\"authors\":\"Jean C. Neto, Ayman Larek, Juan F. Miravet, Minoru Yamaji, Francisco Galindo\",\"doi\":\"10.1002/adom.202501380\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>White light-emitting (WLE) materials are often engineered by tailoring fluorescent dyes to generate balanced emission spectra. In such dye-focused methodologies, the matrix plays a minimal role beyond hosting the emitters. However, this strategy can be unpredictable due to the complexity of modifying dye photophysics with precision. In the work here presented, a matrix-driven approach to WLE is introduced, where the properties of the polymeric host are leveraged to regulate light emission. By adjusting the composition of the polymer network with variation in monomers and cross-linkers, it is possible to control the spatial arrangement and interaction of two dyes, enabling effective color mixing. The system employs readily available monomers, 2-hydroxyethyl methacrylate (HEMA) and poly(ethylene glycol) dimethacrylate (PEGDMA), along with two simple, synthetically accessible dyes: a pyridinium salt and a pyrylium derivative. The resulting hydrogel-based films emit white light with Commission Internationale de l'Éclairage (CIE) chromaticity coordinates at (0.30, 0.33) and a high photoluminescence quantum yield of 0.51. The films are highly transparent, flexible, and suitable for back-illumination, making them excellent candidates for integration into next-generation optoelectronic platforms, such as bendable lighting elements, transparent displays, and wearable light sources. 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Organic, Transparent, and Flexible Films Exhibiting White-Light Emission via Polymer-Network Engineering: A Non-Dye-Centric Strategy
White light-emitting (WLE) materials are often engineered by tailoring fluorescent dyes to generate balanced emission spectra. In such dye-focused methodologies, the matrix plays a minimal role beyond hosting the emitters. However, this strategy can be unpredictable due to the complexity of modifying dye photophysics with precision. In the work here presented, a matrix-driven approach to WLE is introduced, where the properties of the polymeric host are leveraged to regulate light emission. By adjusting the composition of the polymer network with variation in monomers and cross-linkers, it is possible to control the spatial arrangement and interaction of two dyes, enabling effective color mixing. The system employs readily available monomers, 2-hydroxyethyl methacrylate (HEMA) and poly(ethylene glycol) dimethacrylate (PEGDMA), along with two simple, synthetically accessible dyes: a pyridinium salt and a pyrylium derivative. The resulting hydrogel-based films emit white light with Commission Internationale de l'Éclairage (CIE) chromaticity coordinates at (0.30, 0.33) and a high photoluminescence quantum yield of 0.51. The films are highly transparent, flexible, and suitable for back-illumination, making them excellent candidates for integration into next-generation optoelectronic platforms, such as bendable lighting elements, transparent displays, and wearable light sources. This strategy highlights the untapped potential of polymer matrices in fine-tuning emissive behavior.
期刊介绍:
Advanced Optical Materials, part of the esteemed Advanced portfolio, is a unique materials science journal concentrating on all facets of light-matter interactions. For over a decade, it has been the preferred optical materials journal for significant discoveries in photonics, plasmonics, metamaterials, and more. The Advanced portfolio from Wiley is a collection of globally respected, high-impact journals that disseminate the best science from established and emerging researchers, aiding them in fulfilling their mission and amplifying the reach of their scientific discoveries.