Muhammad Miqdad Hassan , F.F. Alharbi , Hala M. Abo-Dief , Eman Alzahrani , Abhinav Kumar
{"title":"超级电容器用聚苯胺电极纳米结构氧化铈的设计与合成","authors":"Muhammad Miqdad Hassan , F.F. Alharbi , Hala M. Abo-Dief , Eman Alzahrani , Abhinav Kumar","doi":"10.1016/j.jorganchem.2025.123852","DOIUrl":null,"url":null,"abstract":"<div><div>The current focus of scientific study is to overcome energy storage problems. For this purpose, supercapacitor (SC) was choosen due to its high performance and long stability. The main part of SC is its electrodes. Transition metal oxides (TMOs) are attractive SC electrodes due to their high specific capacitance (C<sub>s</sub>) and low cost. While single metal oxide shows smaller surface area, to overcome this issue we fabricate CeO<sub>2</sub>/PANI nanocomposite by employing a quick and effective single-step sonification technique. Physical characterization like X-ray diffraction (XRD) was used to analyze structural nature and scanning electron microscopy (SEM) to examine morphology of manufactured materials, specifically CeO<sub>2</sub>/PANI nanocomposite. Electrochemical properties of the nanocomposite CeO<sub>2</sub>/PANI showed outstanding C<sub>s</sub> 1076.05 F/g and E<sub>d</sub> (36.47 Wh/kg) at 1 A/g. Furthermore, CeO<sub>2</sub>/PANI displays excellent electrochemical capacities with great potential for innovation in the future. The present research shows that composition of polyaniline (PANI) and CeO<sub>2</sub> increases energy storage efficiency and indicates that it can be utilized in SCs in future.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1041 ","pages":"Article 123852"},"PeriodicalIF":2.1000,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design and synthesis of nanostructured cerium oxide anchored on polyaniline electrode for supercapacitors\",\"authors\":\"Muhammad Miqdad Hassan , F.F. Alharbi , Hala M. Abo-Dief , Eman Alzahrani , Abhinav Kumar\",\"doi\":\"10.1016/j.jorganchem.2025.123852\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The current focus of scientific study is to overcome energy storage problems. For this purpose, supercapacitor (SC) was choosen due to its high performance and long stability. The main part of SC is its electrodes. Transition metal oxides (TMOs) are attractive SC electrodes due to their high specific capacitance (C<sub>s</sub>) and low cost. While single metal oxide shows smaller surface area, to overcome this issue we fabricate CeO<sub>2</sub>/PANI nanocomposite by employing a quick and effective single-step sonification technique. Physical characterization like X-ray diffraction (XRD) was used to analyze structural nature and scanning electron microscopy (SEM) to examine morphology of manufactured materials, specifically CeO<sub>2</sub>/PANI nanocomposite. Electrochemical properties of the nanocomposite CeO<sub>2</sub>/PANI showed outstanding C<sub>s</sub> 1076.05 F/g and E<sub>d</sub> (36.47 Wh/kg) at 1 A/g. Furthermore, CeO<sub>2</sub>/PANI displays excellent electrochemical capacities with great potential for innovation in the future. The present research shows that composition of polyaniline (PANI) and CeO<sub>2</sub> increases energy storage efficiency and indicates that it can be utilized in SCs in future.</div></div>\",\"PeriodicalId\":374,\"journal\":{\"name\":\"Journal of Organometallic Chemistry\",\"volume\":\"1041 \",\"pages\":\"Article 123852\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2025-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Organometallic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022328X25003444\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022328X25003444","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Design and synthesis of nanostructured cerium oxide anchored on polyaniline electrode for supercapacitors
The current focus of scientific study is to overcome energy storage problems. For this purpose, supercapacitor (SC) was choosen due to its high performance and long stability. The main part of SC is its electrodes. Transition metal oxides (TMOs) are attractive SC electrodes due to their high specific capacitance (Cs) and low cost. While single metal oxide shows smaller surface area, to overcome this issue we fabricate CeO2/PANI nanocomposite by employing a quick and effective single-step sonification technique. Physical characterization like X-ray diffraction (XRD) was used to analyze structural nature and scanning electron microscopy (SEM) to examine morphology of manufactured materials, specifically CeO2/PANI nanocomposite. Electrochemical properties of the nanocomposite CeO2/PANI showed outstanding Cs 1076.05 F/g and Ed (36.47 Wh/kg) at 1 A/g. Furthermore, CeO2/PANI displays excellent electrochemical capacities with great potential for innovation in the future. The present research shows that composition of polyaniline (PANI) and CeO2 increases energy storage efficiency and indicates that it can be utilized in SCs in future.
期刊介绍:
The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds.
Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome.
The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.