环氧化植物油作为二羟基硬脂酸(DHSA)原料的研究进展

IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL
Intan Suhada Azmi, Siti Mariam A. Rahman, Silvana Dwi Nurherdiana, Norfazilah Abdullah, Muhammad Akhiruddin Zainal Abidin, Mohd Jumain Jalil
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引用次数: 0

摘要

环氧化植物油已成为生产二羟基硬脂酸(DHSA)的一种有前途的可再生原料,二羟基硬脂酸是一种高价值的羟基脂肪酸,在化妆品、润滑剂和生物可降解聚合物等工业应用中得到广泛应用。本文综述了环氧化过程、氧环形成和随后的水解DHSA,强调了过酸氧化作为关键反应途径的作用。分析了影响环氧化效率和DHSA产率的各种因素,包括反应条件、催化剂选择等。同时还讨论了氧环的水解机理。该工艺符合对石化资源可持续替代品日益增长的需求,具有可生物降解性和多功能性等优势,可用于润滑剂和聚合物等工业应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

An overview of epoxidized vegetable oil as feedstock for Dihyrdroxystearic acid (DHSA) production

An overview of epoxidized vegetable oil as feedstock for Dihyrdroxystearic acid (DHSA) production

An overview of epoxidized vegetable oil as feedstock for Dihyrdroxystearic acid (DHSA) production

An overview of epoxidized vegetable oil as feedstock for Dihyrdroxystearic acid (DHSA) production

Epoxidized vegetable oils have emerged as a promising renewable feedstock to produce dihydroxystearic acid (DHSA), a high-value hydroxyl fatty acid used in industrial applications such as cosmetics, lubricants, and biodegradable polymers. This review provides a comprehensive overview of the epoxidation process, oxirane ring formation, and subsequent hydrolysis to DHSA, emphasizing the role of peracid oxidation as a key reaction pathway. Various factors affecting epoxidation efficiency and DHSA yield, including reaction conditions, catalyst selection, and are critically analyzed. The hydrolysis mechanism of oxirane rings leading to DHSA formation is discussed alongside. This process aligns with the rising demand for sustainable alternatives to petrochemical resources, offering advantages such as biodegradability and versatility in industrial applications like lubricants and polymers.

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来源期刊
Environmental Progress & Sustainable Energy
Environmental Progress & Sustainable Energy 环境科学-工程:化工
CiteScore
5.00
自引率
3.60%
发文量
231
审稿时长
4.3 months
期刊介绍: Environmental Progress , a quarterly publication of the American Institute of Chemical Engineers, reports on critical issues like remediation and treatment of solid or aqueous wastes, air pollution, sustainability, and sustainable energy. Each issue helps chemical engineers (and those in related fields) stay on top of technological advances in all areas associated with the environment through feature articles, updates, book and software reviews, and editorials.
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