层状双层氢氧化铝镁吸附磷酸离子的动力学研究

IF 0.6 4区工程技术 Q4 ENGINEERING, CHEMICAL

Theoretical Foundations of Chemical Engineering Pub Date : 2025-09-21 DOI:10.1134/S0040579525700411

D. V. Maiorov

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引用次数: 0

摘要

采用固相相互作用法研究了Mg4Al2(OH)12CO3⋅3H2O层状双氢氧化物对\({\text{PO}}_{4}^{{3 - }}\)离子的吸附性能。发现吸附过程用Langmuir单分子吸附方程最能描述，其动力学用拟一阶方程描述。测定了该过程的活化能，据此得出该过程发生在扩散区。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Kinetics of Phosphate Ion Sorption by Layered Double Magnesium Aluminum Hydroxide

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Kinetics of Phosphate Ion Sorption by Layered Double Magnesium Aluminum Hydroxide

The paper presents the results of studies of the sorption properties of layered double hydroxide of the composition Mg₄Al₂(OH)₁₂CO₃⋅3H₂O, obtained by the solid-phase interaction method, with respect to the \({\text{PO}}_{4}^{{3 - }}\) ion. It is found that the sorption process is most adequately described by the Langmuir monomolecular adsorption equation, and its kinetics is described by a pseudo-first-order equation. The activation energy of the process is determined, based on which is concluded that the process occurs in the diffusion region.

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来源期刊

Theoretical Foundations of Chemical Engineering 工程技术-工程：化工

CiteScore

1.20

自引率

25.00%

发文量

审稿时长

24 months

期刊介绍： Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.