N.M. Bruno , V. Keylin , G. Feichter , A.M. Leary , R.D. Noebe
{"title":"具有大应力诱导各向异性的新型高韧性钴基纳米晶软磁合金","authors":"N.M. Bruno , V. Keylin , G. Feichter , A.M. Leary , R.D. Noebe","doi":"10.1016/j.scriptamat.2025.116998","DOIUrl":null,"url":null,"abstract":"<div><div>Mechanical and magnetic properties for a new Co-base nanocrystalline soft magnetic alloy, Co<sub>80</sub>Fe<sub>1.5</sub>Mn<sub>1.5</sub>Nb<sub>8</sub>Si<sub>2</sub>B<sub>7</sub> at.%, are compared to those of previously studied Co<sub>(80–2x)</sub>-Fe<sub>x</sub>−Mn<sub>x</sub>-Nb<sub>4</sub>-Si<sub>2</sub>-B<sub>14</sub> at.% (where <em>x</em> = 2.3, 2.7, and 4) as cast and stress-annealed ribbons. The new alloy exhibits a fracture toughness,<span><math><mrow><mspace></mspace><msub><mi>K</mi><mi>C</mi></msub></mrow></math></span>, of 58 MPa<span><math><msqrt><mi>m</mi></msqrt></math></span> after stress-annealing at 500 °C and a stress-induced/stress-normalized magnetic anisotropy, <span><math><mrow><msub><mi>K</mi><mi>u</mi></msub><mo>/</mo><mi>σ</mi></mrow></math></span>, of 0.094 kJ/(MPa<span><math><mrow><mo>·</mo><msup><mrow><mi>m</mi></mrow><mn>3</mn></msup></mrow></math></span>), i.e., a value nearly double that of other Co-base nanocrystalline alloys. The bulk magnetostriction, <span><math><msubsup><mi>λ</mi><mi>s</mi><mrow><mi>b</mi><mi>u</mi><mi>l</mi><mi>k</mi></mrow></msubsup></math></span>, of the new composition was also determined to be approximately zero after stress-annealing. XRD was used to identify the nanocrystalline phases in annealed ribbon, and the fracture morphologies were observed via SEM. The fracture surfaces of tough and brittle annealed ribbons contained morphologies indicative of local melting and traditional shear hackle/mist patterns, respectively, suggesting that the iron and manganese concentrations in Co-based nanocomposites influence the alloy’s mechanical properties and processability.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"271 ","pages":"Article 116998"},"PeriodicalIF":5.6000,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A new high-toughness Co-based nanocrystalline soft-magnetic alloy capable of large stress-induced anisotropy\",\"authors\":\"N.M. Bruno , V. Keylin , G. Feichter , A.M. Leary , R.D. Noebe\",\"doi\":\"10.1016/j.scriptamat.2025.116998\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Mechanical and magnetic properties for a new Co-base nanocrystalline soft magnetic alloy, Co<sub>80</sub>Fe<sub>1.5</sub>Mn<sub>1.5</sub>Nb<sub>8</sub>Si<sub>2</sub>B<sub>7</sub> at.%, are compared to those of previously studied Co<sub>(80–2x)</sub>-Fe<sub>x</sub>−Mn<sub>x</sub>-Nb<sub>4</sub>-Si<sub>2</sub>-B<sub>14</sub> at.% (where <em>x</em> = 2.3, 2.7, and 4) as cast and stress-annealed ribbons. The new alloy exhibits a fracture toughness,<span><math><mrow><mspace></mspace><msub><mi>K</mi><mi>C</mi></msub></mrow></math></span>, of 58 MPa<span><math><msqrt><mi>m</mi></msqrt></math></span> after stress-annealing at 500 °C and a stress-induced/stress-normalized magnetic anisotropy, <span><math><mrow><msub><mi>K</mi><mi>u</mi></msub><mo>/</mo><mi>σ</mi></mrow></math></span>, of 0.094 kJ/(MPa<span><math><mrow><mo>·</mo><msup><mrow><mi>m</mi></mrow><mn>3</mn></msup></mrow></math></span>), i.e., a value nearly double that of other Co-base nanocrystalline alloys. The bulk magnetostriction, <span><math><msubsup><mi>λ</mi><mi>s</mi><mrow><mi>b</mi><mi>u</mi><mi>l</mi><mi>k</mi></mrow></msubsup></math></span>, of the new composition was also determined to be approximately zero after stress-annealing. XRD was used to identify the nanocrystalline phases in annealed ribbon, and the fracture morphologies were observed via SEM. The fracture surfaces of tough and brittle annealed ribbons contained morphologies indicative of local melting and traditional shear hackle/mist patterns, respectively, suggesting that the iron and manganese concentrations in Co-based nanocomposites influence the alloy’s mechanical properties and processability.</div></div>\",\"PeriodicalId\":423,\"journal\":{\"name\":\"Scripta Materialia\",\"volume\":\"271 \",\"pages\":\"Article 116998\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2025-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scripta Materialia\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1359646225004609\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646225004609","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A new high-toughness Co-based nanocrystalline soft-magnetic alloy capable of large stress-induced anisotropy
Mechanical and magnetic properties for a new Co-base nanocrystalline soft magnetic alloy, Co80Fe1.5Mn1.5Nb8Si2B7 at.%, are compared to those of previously studied Co(80–2x)-Fex−Mnx-Nb4-Si2-B14 at.% (where x = 2.3, 2.7, and 4) as cast and stress-annealed ribbons. The new alloy exhibits a fracture toughness,, of 58 MPa after stress-annealing at 500 °C and a stress-induced/stress-normalized magnetic anisotropy, , of 0.094 kJ/(MPa), i.e., a value nearly double that of other Co-base nanocrystalline alloys. The bulk magnetostriction, , of the new composition was also determined to be approximately zero after stress-annealing. XRD was used to identify the nanocrystalline phases in annealed ribbon, and the fracture morphologies were observed via SEM. The fracture surfaces of tough and brittle annealed ribbons contained morphologies indicative of local melting and traditional shear hackle/mist patterns, respectively, suggesting that the iron and manganese concentrations in Co-based nanocomposites influence the alloy’s mechanical properties and processability.
期刊介绍:
Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.