一种用于与富勒烯超分子组装的掺杂硅纳米碗

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-09-18 DOI:10.1021/acs.orglett.5c03421

Bo Yang, , , Yixun Sun, , , Jiale Hu, , , Muhua Chen, , , Xin Wang, , , Juan Fan, , , Huaming Sun, , , Jing Li*, , and , Junfa Wei*,

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引用次数: 0

摘要

以六氯三氟壬烯为原料，经3次钯催化硅环法制备了掺杂硅的纳米碗——三硅亚苏壬烯1。在芳香骨架中加入硅环会在循环伏安法和低LUMO水平中产生新的还原波。碗1与富勒烯C60和C70表现出高结合亲和力，形成具有独特包装排列的超分子配合物1、C60和(1)2、C70。值得注意的是，(1)2、C70在晶体中具有罕见的蛤状结构，完全不同于它在溶液中的结合行为。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A Silicon-Doped Nanographenic Bowl for Supramolecular Assembly with Fullerenes

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A Silicon-Doped Nanographenic Bowl for Supramolecular Assembly with Fullerenes

A silicon-doped nanographenic bowl, trisilasupersumanene 1, was synthesized via a 3-fold palladium-catalyzed sila-annulation from the hexachlorinated trifluorenocoronene. Incorporating silole rings into the aromatic framework leads to new reduction waves in cyclic voltammetry and low-lying LUMO levels. The bowl 1 exhibits high binding affinity to fullerenes C₆₀ and C₇₀, forming supramolecular complexes 1⊃C₆₀ and (1)₂⊃C₇₀ with unique packing arrangements. Notably, (1)₂⊃C₇₀ features a rare clam-like structure in the crystal, entirely different from its binding behavior in solution.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.