不同类型分散剂对沥青质聚集及沥青质分散稳定性的影响

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
V. K. Korolev, E. S. Iskandarova, A. V. Kosach, R. Z. Safieva
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引用次数: 0

摘要

用两种独立的光学方法表征了两种不同合成分散剂的效果。该研究考察了它们对沥青质聚集(使用标准程序从各种原油中分离出来)和含沥青质模型分散体稳定性的影响。在模型正庚烷/甲苯介质中,两种分散剂对沥青质聚集和分散稳定性的影响有显著差异。一种分散剂不能分散沥青质,因为它在正庚烷介质中自结合成大胶束(半径≥100 nm),从而破坏了体系的稳定。因此,未来分散剂和稳定剂的关键设计标准应该是在非极性介质中最大限度地减少自结合,同时最大限度地提高对沥青质的亲和力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The Effects of Different Types of Dispersants on Asphaltene Aggregation and on the Stability of Asphaltene Dispersions

The Effects of Different Types of Dispersants on Asphaltene Aggregation and on the Stability of Asphaltene Dispersions

The Effects of Different Types of Dispersants on Asphaltene Aggregation and on the Stability of Asphaltene Dispersions

The effects of two different synthetic dispersants were characterized using two independent optical methods. The study examined their impact on both the aggregation of asphaltenes (isolated from various crude oils using a standard procedure) and the stability of model asphaltene-containing dispersions. In the model n-heptane/toluene medium, the two dispersants had markedly different effects on asphaltene aggregation and dispersion stability. One dispersant failed to disperse asphaltenes because it self-associated into large micelles (≥100 nm in radius) in the n-heptane medium, thereby destabilizing the system. Consequently, a key design criterion for future dispersants and stabilizers should be a molecular structure that minimizes self-association in nonpolar media while maximizing affinity for asphaltenes.

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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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