{"title":"改性石墨烯纳米片(GNPs)在表面活性剂水溶液中的表面修饰和分散性","authors":"Faping Li, Peipei Qi, Lisheng Liu, Huan Wang","doi":"10.1134/S0036024425701407","DOIUrl":null,"url":null,"abstract":"<p>The dispersion of modified GNPs plays a crucial role in their performance within composite materials. In the study, two kinds of surfactants, including odium dodecyl sulfate (SDS) and polyoxyethylene nonylphenyl ether (CO890), are employed to research the dispersion of modified GNPs in aqueous solution. In addition, ultrasonic treatment is used to prepare a uniform suspension of modified GNPs, and the dispersion quality is evaluated through ultraviolet absorbance, zeta potential, surface tension, and TEM imaging. The experimental results indicate that the zeta potential and surface tension stabilize at CO890 and SDS concentrations of approximately 0.5 and 0.7g/L, respectively. This suggests that the ideal CO890 to modified GNPs ratio is 5 : 2, while the optimal SDS to modified GNPs ratio is 7 : 2, which results in the highest dispersion efficiency for the modified GNPs. The TEM images illustrate that the modified GNPs can be effectively dispersed in aqueous surfactant solution combined with ultrasonic treatment.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 9","pages":"2178 - 2183"},"PeriodicalIF":0.8000,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Surface Decoration and Dispersibility of Modified Graphene Nanoplatelets (GNPs) in Aqueous Surfactant Solution\",\"authors\":\"Faping Li, Peipei Qi, Lisheng Liu, Huan Wang\",\"doi\":\"10.1134/S0036024425701407\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The dispersion of modified GNPs plays a crucial role in their performance within composite materials. In the study, two kinds of surfactants, including odium dodecyl sulfate (SDS) and polyoxyethylene nonylphenyl ether (CO890), are employed to research the dispersion of modified GNPs in aqueous solution. In addition, ultrasonic treatment is used to prepare a uniform suspension of modified GNPs, and the dispersion quality is evaluated through ultraviolet absorbance, zeta potential, surface tension, and TEM imaging. The experimental results indicate that the zeta potential and surface tension stabilize at CO890 and SDS concentrations of approximately 0.5 and 0.7g/L, respectively. This suggests that the ideal CO890 to modified GNPs ratio is 5 : 2, while the optimal SDS to modified GNPs ratio is 7 : 2, which results in the highest dispersion efficiency for the modified GNPs. The TEM images illustrate that the modified GNPs can be effectively dispersed in aqueous surfactant solution combined with ultrasonic treatment.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"99 9\",\"pages\":\"2178 - 2183\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-09-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024425701407\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024425701407","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Surface Decoration and Dispersibility of Modified Graphene Nanoplatelets (GNPs) in Aqueous Surfactant Solution
The dispersion of modified GNPs plays a crucial role in their performance within composite materials. In the study, two kinds of surfactants, including odium dodecyl sulfate (SDS) and polyoxyethylene nonylphenyl ether (CO890), are employed to research the dispersion of modified GNPs in aqueous solution. In addition, ultrasonic treatment is used to prepare a uniform suspension of modified GNPs, and the dispersion quality is evaluated through ultraviolet absorbance, zeta potential, surface tension, and TEM imaging. The experimental results indicate that the zeta potential and surface tension stabilize at CO890 and SDS concentrations of approximately 0.5 and 0.7g/L, respectively. This suggests that the ideal CO890 to modified GNPs ratio is 5 : 2, while the optimal SDS to modified GNPs ratio is 7 : 2, which results in the highest dispersion efficiency for the modified GNPs. The TEM images illustrate that the modified GNPs can be effectively dispersed in aqueous surfactant solution combined with ultrasonic treatment.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.