用于混合离子电子电导率的乙二醇功能化阶梯型低聚苯胺衍生物的合成。

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-09-16 DOI:10.1021/acs.orglett.5c03535

Geunmoo Song, , , Djavdat Azizov, , , Arnab Ghosh, , and , Lei Fang*,

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引用次数: 0

摘要

通过优化的合成策略，高收率合成了两个具有亲水性低聚乙二醇侧链的阶梯型低聚苯胺衍生物，从而研究了侧链对混合离子电子电导率的影响。较短的乙二醇链在低湿度（约45% RH）条件下的电导率提高了1个数量级，而在高湿度（约97% RH）条件下，两者的电导率都提高了约2个数量级。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of Glycol-Functionalized Ladder-Type Oligoaniline Derivatives for Mixed Ionic–Electronic Conductivity

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Synthesis of Glycol-Functionalized Ladder-Type Oligoaniline Derivatives for Mixed Ionic–Electronic Conductivity

Two ladder-type oligoaniline derivatives with hydrophilic oligoethylene glycol side chains were synthesized in high yields via an optimized synthetic strategy, enabling investigation of side-chain effects on mixed ionic–electronic conductivity. Shorter glycol chains yielded conductivities 1 order of magnitude higher under low-humidity (ca. 45% RH) conditions, while both exhibited conductivity increases of approximately 2 orders of magnitude under high-humidity (ca. 97% RH) conditions.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.