Spencer D. Zeigler , Rebecca M. Flowers , D. Graham Pearson , Liam Courtney-Davies , Bruce A. Kjarsgaard , Stephen H. Richardson , Kaden Berkhahn , James R. Metcalf , Izaac Cabral-Neto
{"title":"配对巨晶锆石(U- th)/He和U/Pb定年揭示了金伯利岩喷发年龄、侵位史和巨晶成因","authors":"Spencer D. Zeigler , Rebecca M. Flowers , D. Graham Pearson , Liam Courtney-Davies , Bruce A. Kjarsgaard , Stephen H. Richardson , Kaden Berkhahn , James R. Metcalf , Izaac Cabral-Neto","doi":"10.1016/j.chemgeo.2025.123033","DOIUrl":null,"url":null,"abstract":"<div><div>The timing of the processes occurring in the lithosphere during the ascent and eruption of kimberlites has been challenging to ascertain. Here, we present a novel application of paired (U-Th)/He and U/Pb geochronology on megacrystic zircon to date both the crystallization of the megacryst suite and the host kimberlite eruption. Unlike Pb, He is not retained in the crystal at temperatures >250 °C. For megacrystic zircon that crystallizes in the mantle, He retention begins upon kimberlite eruption such that the zircon (U-Th)/He (ZHe) dates should record kimberlite emplacement. We collected cathodoluminescence, trace element, U/Pb, and (U-Th)/He data for nine megacrystic zircon from five kimberlites: Diavik and Panda (Canada), Juína and Batovi-9 (Brazil), and Monastery (South Africa). For all zircon except from Diavik, ZHe and U/Pb dates overlap within uncertainty, indicating megacryst crystallization during or shortly before kimberlite eruption, and suggesting a genetic link between the kimberlite magma and megacryst suite. For Diavik zircon, the ZHe dates are ∼2.5 Gyr younger than the U/Pb dates, documenting that the megacrysts and the host kimberlite magma are genetically unrelated. ZHe dates from three of the kimberlites overlap with eruption ages interpreted from other methods. However, for Panda and Monastery, our paired ZHe-U/Pb dates differ from previous results, consistent with multiple eruptions over ∼5 Myr and implying that protracted eruptive phases may be more common than previously thought. Our work shows that (U-Th)/He dating of megacrystic zircon accurately dates kimberlite emplacement, and when coupled with U/Pb dating can yield insights into megacryst-kimberlite relationships.</div></div>","PeriodicalId":9847,"journal":{"name":"Chemical Geology","volume":"695 ","pages":"Article 123033"},"PeriodicalIF":3.6000,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Paired megacrystic zircon (U-Th)/He and U/Pb dating reveals kimberlite eruption ages, protracted emplacement histories, and insights into megacryst genesis\",\"authors\":\"Spencer D. Zeigler , Rebecca M. Flowers , D. Graham Pearson , Liam Courtney-Davies , Bruce A. Kjarsgaard , Stephen H. Richardson , Kaden Berkhahn , James R. Metcalf , Izaac Cabral-Neto\",\"doi\":\"10.1016/j.chemgeo.2025.123033\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The timing of the processes occurring in the lithosphere during the ascent and eruption of kimberlites has been challenging to ascertain. Here, we present a novel application of paired (U-Th)/He and U/Pb geochronology on megacrystic zircon to date both the crystallization of the megacryst suite and the host kimberlite eruption. Unlike Pb, He is not retained in the crystal at temperatures >250 °C. For megacrystic zircon that crystallizes in the mantle, He retention begins upon kimberlite eruption such that the zircon (U-Th)/He (ZHe) dates should record kimberlite emplacement. We collected cathodoluminescence, trace element, U/Pb, and (U-Th)/He data for nine megacrystic zircon from five kimberlites: Diavik and Panda (Canada), Juína and Batovi-9 (Brazil), and Monastery (South Africa). For all zircon except from Diavik, ZHe and U/Pb dates overlap within uncertainty, indicating megacryst crystallization during or shortly before kimberlite eruption, and suggesting a genetic link between the kimberlite magma and megacryst suite. For Diavik zircon, the ZHe dates are ∼2.5 Gyr younger than the U/Pb dates, documenting that the megacrysts and the host kimberlite magma are genetically unrelated. ZHe dates from three of the kimberlites overlap with eruption ages interpreted from other methods. However, for Panda and Monastery, our paired ZHe-U/Pb dates differ from previous results, consistent with multiple eruptions over ∼5 Myr and implying that protracted eruptive phases may be more common than previously thought. Our work shows that (U-Th)/He dating of megacrystic zircon accurately dates kimberlite emplacement, and when coupled with U/Pb dating can yield insights into megacryst-kimberlite relationships.</div></div>\",\"PeriodicalId\":9847,\"journal\":{\"name\":\"Chemical Geology\",\"volume\":\"695 \",\"pages\":\"Article 123033\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0009254125004231\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Geology","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009254125004231","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Paired megacrystic zircon (U-Th)/He and U/Pb dating reveals kimberlite eruption ages, protracted emplacement histories, and insights into megacryst genesis
The timing of the processes occurring in the lithosphere during the ascent and eruption of kimberlites has been challenging to ascertain. Here, we present a novel application of paired (U-Th)/He and U/Pb geochronology on megacrystic zircon to date both the crystallization of the megacryst suite and the host kimberlite eruption. Unlike Pb, He is not retained in the crystal at temperatures >250 °C. For megacrystic zircon that crystallizes in the mantle, He retention begins upon kimberlite eruption such that the zircon (U-Th)/He (ZHe) dates should record kimberlite emplacement. We collected cathodoluminescence, trace element, U/Pb, and (U-Th)/He data for nine megacrystic zircon from five kimberlites: Diavik and Panda (Canada), Juína and Batovi-9 (Brazil), and Monastery (South Africa). For all zircon except from Diavik, ZHe and U/Pb dates overlap within uncertainty, indicating megacryst crystallization during or shortly before kimberlite eruption, and suggesting a genetic link between the kimberlite magma and megacryst suite. For Diavik zircon, the ZHe dates are ∼2.5 Gyr younger than the U/Pb dates, documenting that the megacrysts and the host kimberlite magma are genetically unrelated. ZHe dates from three of the kimberlites overlap with eruption ages interpreted from other methods. However, for Panda and Monastery, our paired ZHe-U/Pb dates differ from previous results, consistent with multiple eruptions over ∼5 Myr and implying that protracted eruptive phases may be more common than previously thought. Our work shows that (U-Th)/He dating of megacrystic zircon accurately dates kimberlite emplacement, and when coupled with U/Pb dating can yield insights into megacryst-kimberlite relationships.
期刊介绍:
Chemical Geology is an international journal that publishes original research papers on isotopic and elemental geochemistry, geochronology and cosmochemistry.
The Journal focuses on chemical processes in igneous, metamorphic, and sedimentary petrology, low- and high-temperature aqueous solutions, biogeochemistry, the environment and cosmochemistry.
Papers that are field, experimentally, or computationally based are appropriate if they are of broad international interest. The Journal generally does not publish papers that are primarily of regional or local interest, or which are primarily focused on remediation and applied geochemistry.
The Journal also welcomes innovative papers dealing with significant analytical advances that are of wide interest in the community and extend significantly beyond the scope of what would be included in the methods section of a standard research paper.