钼取代增强过硫酸盐在lafeo3基催化剂中的活化作用:反应种类和催化机理

IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Yumei Li, Bingqian Deng, Jiexin Wang, Jialong Li, Wenbin An, Jian Fan, Peng Sun
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引用次数: 0

摘要

合成了一种钼改性LaFeO3 (LFMO)钙钛矿催化剂,用于活化过氧单硫酸盐(PMS)降解溶液中的吲哚。采用XRD、SEM和XPS对催化剂进行了表征。结果表明,与未经改性的LaFeO3相比,LFMO具有更高的比表面积和更多的催化活性位点。XPS分析表明,PMS的活化是由Fe2+/Fe3+和Mo4+/Mo6+还原氧化循环介导的。钼取代产生的氧空位作为反应位点,加速了PMS的解离和活性氧的生成。通过化学猝灭实验和EPR光谱分析对其机理进行了阐明,强调了非自由基在吲哚的去除中起重要作用。在最优反应条件下,吲哚在30 min内的降解效率达到90.53%,对无机阴离子和天然有机物具有较强的抗干扰性。LFMO颗粒在连续五个循环中表现出持续的催化活性和稳定性。该LFMO/PMS系统为基于PMS的非自由基降解途径的发展提供了有价值的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Molybdenum substitution for enhanced activation of persulfate in LaFeO3-based catalysts: reaction species and catalytic mechanism

A molybdenum (Mo)-modified LaFeO3 (LFMO) perovskite catalyst was synthesized to activate peroxymonosulfate (PMS) for the degradation of indole in solution. The catalyst was characterized by XRD, SEM, and XPS. Results indicate that LFMO possesses a higher specific surface area and more catalytic active sites compared to unmodified LaFeO3. XPS analysis reveals that the activation of PMS is mediated by Fe2+/Fe3+ and Mo4+/Mo6+ reduction–oxidation cycles. Oxygen vacancies generated by molybdenum substitution serve as reaction sites, which accelerate the dissociation of PMS and the production of reactive oxygen species. Chemical quenching experiments and EPR spectroscopic analyses were employed to elucidate the mechanism, highlighting the significant role of non-radical species in the removal of indole. Under optimal reaction conditions, the degradation efficiency of indole reached 90.53% within 30 min, demonstrating strong anti-interference against inorganic anions and natural organic matter. LFMO particles exhibit sustained catalytic activity and stability over five consecutive cycles. This LFMO/PMS system provides valuable insights for the development of non-radical degradation pathways based on PMS.

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来源期刊
Frontiers of Materials Science
Frontiers of Materials Science MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
4.20
自引率
3.70%
发文量
515
期刊介绍: Frontiers of Materials Science is a peer-reviewed international journal that publishes high quality reviews/mini-reviews, full-length research papers, and short Communications recording the latest pioneering studies on all aspects of materials science. It aims at providing a forum to promote communication and exchange between scientists in the worldwide materials science community. The subjects are seen from international and interdisciplinary perspectives covering areas including (but not limited to): Biomaterials including biomimetics and biomineralization; Nano materials; Polymers and composites; New metallic materials; Advanced ceramics; Materials modeling and computation; Frontier materials synthesis and characterization; Novel methods for materials manufacturing; Materials performance; Materials applications in energy, information and biotechnology.
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