构象预组织笼能增强水中阴离子结合

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-09-11 DOI:10.1021/acs.orglett.5c03094

Yueyan Kuang, , , Yating Wu, , , Yaqi Zhang, , , Hua Tang, , , Chenqi Ge, , , Ze Cao, , , Yuyang Lu, , , Hongye Wang, , , Jiyong Liu, , , Weixiang Chen*, , , Hongliang Chen*, , and , Hao Li*,

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引用次数: 0

摘要

利用动态键和反应位的空间预组织，定量地自组装了六价笼。这种预组织也创造了一个更坚硬的腔，与体积较小的对应物相比，增强了阴离子的结合。这个笼子甚至能识别高度水合的阴离子，比如水中的Cl。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Conformationally Preorganized Cage Enables Enhanced Anion Binding in Water

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Conformationally Preorganized Cage Enables Enhanced Anion Binding in Water

A hexacationic cage was self-assembled quantitatively using a dynamic bond and steric preorganization of reaction sites. This preorganization also creates a more rigid cavity, enhancing anion binding compared to a less bulky counterpart. The cage even recognizes highly hydrated anions like Cl^– in water.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.