(Z)-2-(6-氯咪唑[1,2-a]吡啶-2-基)-3-[4-(二甲基氨基)苯基]丙腈的合成与晶体结构

IF 0.6 Q4 CRYSTALLOGRAPHY
Ludovic Akonan , Eric Ziki , Deto Ursul Jean-Paul N’guessan , Songuigama Coulibaly , Mahama Ouattara , Viviane Adohi-Krou
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引用次数: 0

摘要

在低温(100 K)下测定了标题化合物C18H15ClN4的结构。在晶体中,分子通过C-H⋯N和C-H⋯Cl分子间氢键连接,形成沿[010]方向延伸的网络。此外,C-H π和π-π堆叠相互作用以及分子间接触有助于结构的内聚。Hirshfeld表面分析表明,表面对H⋯H、H⋯N/ N⋯H、H⋯C/C⋯H、H⋯Cl/Cl⋯H和C⋯C接触的贡献分别为30.2、19.9、28.6、12.2和3.7%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis and crystal structure of (Z)-2-(6-chloroimidazo[1,2-a]pyridin-2-yl)-3-[4-(di­methyl­amino)phen­yl]acrylo­nitrile

Synthesis and crystal structure of (Z)-2-(6-chloroimidazo[1,2-a]pyridin-2-yl)-3-[4-(di­methyl­amino)phen­yl]acrylo­nitrile

Synthesis and crystal structure of (Z)-2-(6-chloroimidazo[1,2-a]pyridin-2-yl)-3-[4-(di­methyl­amino)phen­yl]acrylo­nitrile

Synthesis and crystal structure of (Z)-2-(6-chloroimidazo[1,2-a]pyridin-2-yl)-3-[4-(di­methyl­amino)phen­yl]acrylo­nitrile
The structure of the title compound was determined at 100 K. In the crystal, the mol­ecules are connected through C—H⋯N and C—H⋯Cl inter­molecular hydrogen bonds generating a network that extend along the [010] direction. I
The structure of the title compound, C18H15ClN4, was determined at low temperature (100 K). In the crystal, the mol­ecules are connected through C—H⋯N and C—H⋯Cl inter­molecular hydrogen bonds generating a network that extend along the [010] direction. In addition, C—H⋯π and π–π stacking inter­actions as well as inter­molecular contacts contribute to the cohesion of the structure. Hirshfeld surface analysis indicates that the contributions to the surface for the H⋯H, H⋯N/ N⋯H, H⋯C/C⋯H, H⋯Cl/Cl⋯H and C⋯C contacts are 30.2, 19.9, 28.6, 12.2 and 3.7%, respectively.
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来源期刊
CiteScore
1.90
自引率
0.00%
发文量
351
审稿时长
3 weeks
期刊介绍: Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.
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