锂离子电池用MWCNTs膜基负极材料银纳米线的合成与表征

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
S. Shahriari, F. Mollaamin, M. Dehghandar, G. Arab, S. Mohammadi, M. Monajjemi
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引用次数: 0

摘要

随着高密度、高功率微电子产品的发展,迫切需要提高电子浆料的电导率和导热性,以达到对封装材料的新要求。如今,锂离子电池惊人地应用于我们生活的各个方面。随着锂离子电池的广泛应用,从阴极、阳极、电解质材料等方面对锂离子电池的效率提出了更高的技术要求。本文设计了一种新的Ag-MWCNTs的合成方法,并制备了Ag纳米线与多壁碳纳米管(MWCNTs)复合材料。MWCNTs/Sn和Ag-NWs核壳具有显著的结构特征,电导率增强,锂离子扩散距离缩短,电化学反应活跃面积增大。因此,MWCNTs/Ag-NWs/Sn复合电极在高容量、长循环寿命和优异的倍率性能方面表现出更好的锂存储性能。这项工作的目的是基于未来纳米技术对锂离子电池的必要性;因此,Ag-MWCNTs的加入有效地改善了浆料的电学、热学和机械性能,使其成为未来新型包装材料的一个有前景和竞争力的选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis and Characterization of Silver Nano Wires (Ag-NWs) on MWCNTs Film Based Anode Materials for Li-Ion Batteries

Synthesis and Characterization of Silver Nano Wires (Ag-NWs) on MWCNTs Film Based Anode Materials for Li-Ion Batteries

Synthesis and Characterization of Silver Nano Wires (Ag-NWs) on MWCNTs Film Based Anode Materials for Li-Ion Batteries

With the development of microelectronics products with high density and high power, it is urgent to improve the electrical and thermal conductivity of electronic paste to achieve the new requirements of packaging materials. In this days Lithium ion batteries amazingly applied in various aspects of our life. With the wide application of lithium ion battery, the lithium ion battery efficiency requires higher technology in view point of cathodic, anodic, and electrolytes materials. In this work, a new synthesis method of Ag-MWCNTs was designed, as well as a composite of Ag nanowires combination with Multi wall carbon Nano tubes (MWCNTs) were fabricated. The MWCNTs/Sn and Ag-NWs core-shell presents remarkable structural features with enhanced conductivity, shortened the Li-ions diffusion distance, and more active area for electrochemical reactions. As a consequence, MWCNTs/Ag-NWs/Sn composite electrode exhibits improved lithium storage properties in terms of high capacity, long cycle life, and excellent rate performance. The objective of this work is based on necessity of future nano technology for lithium ion batteries; therefore, the addition of Ag-MWCNTs effectively improves the electrical, thermal, and mechanical properties of the paste, making it a promising and competitive choice for new packaging materials in the future.

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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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