钒锡促进铂-氧化铝催化剂甲基环己烷脱氢研究

IF 1.4 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2025-09-04 DOI:10.1134/S002315842560018X

A. D. Lozhkin, N. S. Panina, T. M. Buslaeva, L. G. Bruk

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引用次数: 0

摘要

在甲基环己烷脱氢制甲苯反应中，合成了钒和锡为助剂的铂催化剂，并对其进行了研究。得到了甲基环己烷脱氢过程的实验数据，结果与量子化学计算预测的在铂-氧化铝催化剂加氢和脱氢反应中加入钒的协同效应一致。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Methylcyclohexane Dehydrogenation on Platinum–Alumina Catalysts Promoted with Vanadium and Tin

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Methylcyclohexane Dehydrogenation on Platinum–Alumina Catalysts Promoted with Vanadium and Tin

Platinum catalysts with the additives of vanadium and tin were synthesized and studied in the reaction of methylcyclohexane dehydrogenation to toluene. Experimental data were obtained for the process of methylcyclohexane dehydrogenation, which are consistent with the synergistic effect of vanadium addition to a platinum–alumina catalyst in hydrogenation and dehydrogenation reactions, as predicted by quantum-chemical calculations.

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来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.