通过取代模式控制烯醚自由基阳离子的反应活性：电化学诱导Diels-Alder反应的研究

IF 4.2 3区化学 Q2 CHEMISTRY, PHYSICAL

Catalysis Science & Technology Pub Date : 2025-06-16 DOI:10.1039/d4cy01192a

Haruka Morizumi , Yanan Han , Olga S. Bokareva , Robert Francke , Yoshikazu Kitano , Yohei Okada

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引用次数: 0

摘要

烯醚自由基阳离子是各种转化的有趣中间体，但它们的寿命太短，无法用于合成有机转化。在烯醇醚的β位置添加一个额外的甲基可以有效地控制反应活性，导致新的电化学诱导Diels-Alder反应，鉴于底物结构，该反应具有增强的灵活性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Controlling the reactivity of enol ether radical cations via the substitution pattern: investigation into electrochemically induced Diels–Alder reactions†

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Controlling the reactivity of enol ether radical cations via the substitution pattern: investigation into electrochemically induced Diels–Alder reactions†

Enol ether radical cations are interesting intermediates for various transformations, yet their lifetime can be too short to be harnessed for synthetic organic transformations. An additional methyl group installed in the β-position of an enol ether was found to efficiently control the reactivity, leading to novel electrochemically induced Diels–Alder reactions with enhanced flexibility in view of the substrate structure.

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来源期刊

Catalysis Science & Technology CHEMISTRY, PHYSICAL-

CiteScore

8.70

自引率

6.00%

发文量

587

审稿时长

1.5 months

期刊介绍： A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days