Rui Wang, Li-E Gao, Lingsen Zeng, Lilong Yan, Linghao Zhao, Guyue Hu, Li Wang, Haitao Wang
{"title":"白花岗质岩浆中石榴石溶蚀-再沉淀过程及其深远的地球化学影响","authors":"Rui Wang, Li-E Gao, Lingsen Zeng, Lilong Yan, Linghao Zhao, Guyue Hu, Li Wang, Haitao Wang","doi":"10.1016/j.chemgeo.2025.123008","DOIUrl":null,"url":null,"abstract":"Syn-magmatic garnet-bearing and garnet-free leucogranites from the Tethyan Himalaya display pronounced differences in major element, trace element, and Sr<ce:glyph name=\"sbnd\"></ce:glyph>Nd isotope geochemistry, reflecting a complex magmatic evolution process. Compared with biotite-bearing leucogranites, the garnet-bearing leucogranites have (1) relatively higher SiO<ce:inf loc=\"post\">2</ce:inf>, FeO*, and MnO contents; lower Al<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">3</ce:inf>, CaO, P<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">5</ce:inf>, and TiO<ce:inf loc=\"post\">2</ce:inf> contents; and lower A/CNK values; (2) higher Y, Yb, Zr, Hf, and Th contents and lower Ba and Sr contents; (3) notably higher heavy rare earth element contents and more pronounced negative Eu anomalies; and (4) significantly higher <ce:sup loc=\"post\">87</ce:sup>Sr/<ce:sup loc=\"post\">86</ce:sup>Sr(t) ratios and ε<ce:inf loc=\"post\">Nd</ce:inf>(t) ratios. Furthermore, the garnets in the garnet-bearing leucogranites exhibit characteristics typical of magmatic origins. On the basis of field observations and geochemical data, we propose the following model: during migration and intrusion, high-temperature granitic magma that ultimately formed the biotite-bearing leucogranites, incorporated wall rocks, thereby releasing both material and ancient garnet crystals from the wall rocks into the magma. The assimilation of the wall rocks elevated the FeO*, MnO, and HREE contents and Sr<ce:glyph name=\"sbnd\"></ce:glyph>Nd isotopic compositions and ultimately promoted the crystallization of magmatic garnets and the formation of garnet-bearing leucogranites in the Kongbugang area. These observations provide new constraints on the mechanism responsible for the development of geochemical heterogeneities in granites and the mechanism responsible for the formation of magmatic garnets in S-type granites and highly fractionated I-type granites.","PeriodicalId":9847,"journal":{"name":"Chemical Geology","volume":"28 1","pages":"123008"},"PeriodicalIF":3.6000,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Garnet dissolution–reprecipitation processes in leucogranitic magma and their profound geochemical consequences\",\"authors\":\"Rui Wang, Li-E Gao, Lingsen Zeng, Lilong Yan, Linghao Zhao, Guyue Hu, Li Wang, Haitao Wang\",\"doi\":\"10.1016/j.chemgeo.2025.123008\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Syn-magmatic garnet-bearing and garnet-free leucogranites from the Tethyan Himalaya display pronounced differences in major element, trace element, and Sr<ce:glyph name=\\\"sbnd\\\"></ce:glyph>Nd isotope geochemistry, reflecting a complex magmatic evolution process. Compared with biotite-bearing leucogranites, the garnet-bearing leucogranites have (1) relatively higher SiO<ce:inf loc=\\\"post\\\">2</ce:inf>, FeO*, and MnO contents; lower Al<ce:inf loc=\\\"post\\\">2</ce:inf>O<ce:inf loc=\\\"post\\\">3</ce:inf>, CaO, P<ce:inf loc=\\\"post\\\">2</ce:inf>O<ce:inf loc=\\\"post\\\">5</ce:inf>, and TiO<ce:inf loc=\\\"post\\\">2</ce:inf> contents; and lower A/CNK values; (2) higher Y, Yb, Zr, Hf, and Th contents and lower Ba and Sr contents; (3) notably higher heavy rare earth element contents and more pronounced negative Eu anomalies; and (4) significantly higher <ce:sup loc=\\\"post\\\">87</ce:sup>Sr/<ce:sup loc=\\\"post\\\">86</ce:sup>Sr(t) ratios and ε<ce:inf loc=\\\"post\\\">Nd</ce:inf>(t) ratios. Furthermore, the garnets in the garnet-bearing leucogranites exhibit characteristics typical of magmatic origins. 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Garnet dissolution–reprecipitation processes in leucogranitic magma and their profound geochemical consequences
Syn-magmatic garnet-bearing and garnet-free leucogranites from the Tethyan Himalaya display pronounced differences in major element, trace element, and SrNd isotope geochemistry, reflecting a complex magmatic evolution process. Compared with biotite-bearing leucogranites, the garnet-bearing leucogranites have (1) relatively higher SiO2, FeO*, and MnO contents; lower Al2O3, CaO, P2O5, and TiO2 contents; and lower A/CNK values; (2) higher Y, Yb, Zr, Hf, and Th contents and lower Ba and Sr contents; (3) notably higher heavy rare earth element contents and more pronounced negative Eu anomalies; and (4) significantly higher 87Sr/86Sr(t) ratios and εNd(t) ratios. Furthermore, the garnets in the garnet-bearing leucogranites exhibit characteristics typical of magmatic origins. On the basis of field observations and geochemical data, we propose the following model: during migration and intrusion, high-temperature granitic magma that ultimately formed the biotite-bearing leucogranites, incorporated wall rocks, thereby releasing both material and ancient garnet crystals from the wall rocks into the magma. The assimilation of the wall rocks elevated the FeO*, MnO, and HREE contents and SrNd isotopic compositions and ultimately promoted the crystallization of magmatic garnets and the formation of garnet-bearing leucogranites in the Kongbugang area. These observations provide new constraints on the mechanism responsible for the development of geochemical heterogeneities in granites and the mechanism responsible for the formation of magmatic garnets in S-type granites and highly fractionated I-type granites.
期刊介绍:
Chemical Geology is an international journal that publishes original research papers on isotopic and elemental geochemistry, geochronology and cosmochemistry.
The Journal focuses on chemical processes in igneous, metamorphic, and sedimentary petrology, low- and high-temperature aqueous solutions, biogeochemistry, the environment and cosmochemistry.
Papers that are field, experimentally, or computationally based are appropriate if they are of broad international interest. The Journal generally does not publish papers that are primarily of regional or local interest, or which are primarily focused on remediation and applied geochemistry.
The Journal also welcomes innovative papers dealing with significant analytical advances that are of wide interest in the community and extend significantly beyond the scope of what would be included in the methods section of a standard research paper.