具有高胺取代基的新型（2,2′-双）吡啶。合成与性能

IF 0.9 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-08-18 DOI:10.1134/S1070428025602067

A. Rammohan, G. A. Kim, A. P. Krinochkin, Ya. K. Shtaitz, S. E. Vatolina, A. V. Baklykov, T. A. Tseitler, D. S. Kopchuk, G. V. Zyryanov

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引用次数: 0

摘要

在1,2,4-三嗪前体的基础上，提出了一种合成α-位置上含有较高烷基氨基的（2,2 ' -双）吡啶的高效方法。合成序列包括无溶剂反应。合成的化合物在乙腈溶液中表现出光致发光，绝对量子产率高达83.2 %。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

New (2,2′-Bi)pyridines with Higher Amine Substituents. Synthesis and Properties

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New (2,2′-Bi)pyridines with Higher Amine Substituents. Synthesis and Properties

An efficient synthetic approach to (2,2′-bi)pyridines containing higher alkylamino groups at the α-positions has been proposed on the basis of their 1,2,4-triazine precursors. The synthetic sequence included solvent-free reactions. The synthesized compounds in acetonitrile solution showed photoluminescence with an absolute quantum yield of up to 83.2 %.

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.