低温白云岩地热储层增产泡沫酸液体系泡沫稳定性及酸化效果评价

IF 4.6 0 ENERGY & FUELS
Ou Jiang , Xiuhua Zheng , Pei Wu , Luyao Ma , Xu Liu , Pengfei Jin , Pengxiang Zhang , Yang Yang , Haoyu Yu
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引用次数: 0

摘要

酸化可以提高储层产能,与常规酸液相比,泡沫酸液系统既能有效酸化,又能保护储层。然而,由于油气和地热储层的开发条件不同,目前泡沫酸液的应用仅限于油气储层增产。泡沫酸液在地热储层中的变革性应用,可以解决常规酸液在地热储层中存在的有效酸化距离有限、残余流体难以回流等问题。本文以十二烷基硫酸钠(SDS)、椰浆酰胺丙基甜菜碱(CAPB)、十二烷基三甲基溴化铵(DTAB)和十乙二醇单十二烷基醚(DGME)等典型发泡剂,以及不同泡沫稳定剂黄原胶(XC)含量(0.3% ~ 1.2%)为研究对象,建立了泡沫酸性流体体系。通过泡沫稳定性和酸化效果,以及溶解和缓蚀性能,验证了低温(25°C ~ 90°C)地热储层增产的可行性。结果表明,DTAB和DGME在1.2% XC下的泡沫酸液具有所需的泡沫稳定性。泡沫稳定剂的网状微观结构、泡沫体系中较强的分子间作用力以及发泡剂的化学反应稳定性,共同促进了泡沫的稳定性。与非泡沫酸液相比,泡沫酸液显著延缓了酸岩反应,在微观上更均匀地溶解岩屑。溴化物离子(Br−)在DTAB中的存在增强了N80钢的腐蚀,其腐蚀速度高于公认的腐蚀速度。该研究突出了泡沫酸流体体系在低温白云岩地热储层高效增产中的巨大应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Foam stability and acidizing effect evaluation of a foam acid fluid system for low-temperature dolomite geothermal reservoir stimulation
Acidizing improves reservoir productivity, and foam acid fluid systems achieve both effective acidizing and reservoir protection compared to conventionally utilized acid fluids. Nevertheless, the current application of foam acid fluids is restricted to oil-gas reservoir stimulation, owing to the differences in development conditions between oil-gas and geothermal reservoirs. The transformative application of foam acid fluids from oil-gas to geothermal reservoirs can address the problems induced by conventional acid fluids in geothermal reservoirs, such as limited effective acidizing distance and difficulties in flowing back residual fluids. Here, a foam acid fluid system with typical foaming agents, including sodium dodecyl sulfate (SDS), cocoamidopropyl betaine (CAPB), dodecyl trimethyl ammonium bromide (DTAB) and decaethylene glycol monododecyl ether (DGME), with various foam stabilizer xanthan (XC) contents (0.3 %–1.2 %) is proposed. Its feasibility in low-temperature (25 °C−90 °C) geothermal reservoir stimulation is verified through foam stability and acidizing effects, containing dissolution and corrosion inhibition performances. The results shows that the foam acid fluids with DTAB and DGME at 1.2 % XC have a required foam stability. A network micro-structure of foam stabilizers, the stronger intermolecular forces in the foaming system, and the chemical reaction stability of foaming agents, mutually contribute to the foam stability. Compared to non-foam acid fluids, foam acid fluids significantly retards acid-rock reaction, with a more uniform dissolution of the cuttings microscopically. The existence of bromide ion (Br) in DTAB enhances the corrosion of N80 steel, which is above an accepted corrosion speed. This study highlights the great application potential of foam acid fluid system in an efficient stimulation of low-temperature dolomite geothermal reservoirs.
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