非均质油藏分散型颗粒凝胶强化碱提高采收率的适应阈值及机理研究

IF 4.6 0 ENERGY & FUELS
Dongfang Lv , Guang Zhao , Teng Wang , Jinzhong Zhao , Zhe Li , Caili Dai
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引用次数: 0

摘要

在开发分散型颗粒凝胶强化碱(DPGSA)作为非均相复合驱后,重点研究了DPGSA的适应阈值和作用机制。验证了DPGSA的适应阈值,包括温度(25-100°C)、盐度(NaCl 0-200,000 mg/L, CaCl2 0-2200 mg/L)、油粘度(10-200 mPa s)、酸值(0.04-0.44)和渗透率(0.25-1.89 μm2)。研究了DPGSA在油水界面的作用机理。0.7 wt% DPG + 1.6 wt% Na2CO3的界面张力(IFT)初始为0.071 mN/m,时效60 d后降至0.045 mN/m。Na2CO3有利于降低IFT,稳定界面膜。随着DPG浓度的增加,界面膜强度降低6.64% ~ 7.49%,随着时效时间的增加,界面膜强度降低27.01% ~ 27.98%。0.03 ~ 0.1 Hz时,弹性模量(21 ~ 35 mN/m) >;黏性模量(13-17 mN/m),增强了界面膜的动态稳定性。DPG的归一化突破时间为0.39,Na2CO3的归一化突破时间为0.65,有利于Na2CO3进入低渗透层。在低孔隙度(0.01-1 μm)层中,DPGSA的采收率由6.91%提高到54.59%。残余油的聚结、剥离油膜和油乳化是由于DPGSA具有低IFT和高强度的界面膜。本研究阐明了DPGSA的适应性和作用机理,为其在油田的广泛应用奠定了基础。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Adaptation thresholds and mechanistic insights into dispersed particle gel strengthened alkali for enhanced oil recovery in heterogeneous reservoirs
After developing dispersed particle gel strengthened alkali (DPGSA) as a heterogeneous combination flooding, the research focused on adaptation thresholds and mechanisms of action of DPGSA. The adaptation thresholds of DPGSA have been verified, including temperatures (25–100 °C), salinities (0–200,000 mg/L for NaCl and up to 0–2200 mg/L for CaCl2), oil viscosities (10–200 mPa s), acid value (0.04–0.44), and permeabilities (0.25–1.89 μm2). The study investigated the mechanism of DPGSA on the oil-water interface. The interfacial tension (IFT) of 0.7 wt% DPG + 1.6 wt% Na2CO3 is initially 0.071 mN/m, decreasing to 0.045 mN/m after 60 days of aging. Na2CO3 is conducive to low IFT and stable the interfacial membrane. The interfacial membrane strength was reduced by 6.64 %–7.49 % with an increase in DPG concentration, and by 27.01 %–27.98 % with an increase in aging time. At 0.03–0.1 Hz, the elastic modulus (21–35 mN/m) > viscous modulus (13–17 mN/m), enhancing the dynamic stability of the interfacial membrane. The normalized breakthrough time are 0.39 for DPG and 0.65 for Na2CO3, facilitating Na2CO3 entry into low-permeability zones. The recovery rate in low-porosity layers (0.01–1 μm) increased from 6.91 % to 54.59 % with the application of DPGSA. The coalescence of residual oil, stripping oil film, and oil emulsification are due to the low IFT and high-strength interfacial membrane of DPGSA. This study elucidated DPGSA's adaptability and mechanism, facilitating its widespread use in oilfield.
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