Yang Wang , Xian-zhe Ran , Hai Wang , Xu Cheng , Shao-yong Zhi , Dong Liu , Hua-ming Wang
{"title":"通过工艺定制边界工程提高双相钛合金耐高温疲劳性能","authors":"Yang Wang , Xian-zhe Ran , Hai Wang , Xu Cheng , Shao-yong Zhi , Dong Liu , Hua-ming Wang","doi":"10.1016/j.ijfatigue.2025.109195","DOIUrl":null,"url":null,"abstract":"<div><div>The development of high-temperature titanium alloys for aerospace propulsion systems requires good thermostability and fatigue resistance under high temperature loading conditions. This study comparatively investigated the microstructural characteristics and fatigue performance of Ti-6Al-4Zr-4Mo-2Sn-1W-0.2Si duplex titanium alloys fabricated respectively via laser-directed energy deposition additive manufacturing (AM) and conventional forging technologies. The results revealed that the forged titanium alloy contained fine grains with a heterogeneously duplex structure consisting of large-size near-spherical primary α and hard β<sub>t</sub> phases. By contrast, the AMed titanium alloy contained columnar grains with an interior homogenous basketweave structure containing a few unstable high angle boundaries (HABs) and a high ratio of low angle boundaries (LABs). Although the room-temperature tensile strengths of two types of alloys were similar (∼1100 MPa), the AMed titanium alloy suggested superior high temperature mechanical properties with 8 % higher strength retention at 550 °C than the forged alloy (882 vs. 811 MPa). With an increase of total strain amplitude (Δ<em>ε<sub>t</sub></em>), the fatigue life of the specimen was prone to decreasing, associated with the declined texture intensity and activity of basal slip system of (0 0 0 1) [1 1 <span><math><mrow><mover><mrow><mn>2</mn></mrow><mrow><mo>¯</mo></mrow></mover><mspace></mspace></mrow></math></span>0]. Under the same Δ<em>ε<sub>t</sub></em> value of 0.6 %, the high temperature fatigue lives of the AMed alloys were 6–7 times longer than the forged counterparts. Fractographic analysis of the fatigue specimens revealed that surface slip cracking accompanied by oxide formation served as the predominant fatigue crack initiation mechanism, followed by striation patterns observed in crack propagation paths. Compared to the forged alloy, the higher fatigue properties of the AMed titanium alloy were mainly attributed to a higher thermostability and optimum microstructure design (fewer HABs and high ratio of LABs) resisting fatigue cracking. These findings offer a guide for the fabrication of next-generation titanium alloys requiring simultaneous high-temperature strength and fatigue resistance in aerospace applications.</div></div>","PeriodicalId":14112,"journal":{"name":"International Journal of Fatigue","volume":"201 ","pages":"Article 109195"},"PeriodicalIF":6.8000,"publicationDate":"2025-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhancing high-temperature fatigue resistance in duplex titanium alloys via process-tailored boundary engineering\",\"authors\":\"Yang Wang , Xian-zhe Ran , Hai Wang , Xu Cheng , Shao-yong Zhi , Dong Liu , Hua-ming Wang\",\"doi\":\"10.1016/j.ijfatigue.2025.109195\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The development of high-temperature titanium alloys for aerospace propulsion systems requires good thermostability and fatigue resistance under high temperature loading conditions. This study comparatively investigated the microstructural characteristics and fatigue performance of Ti-6Al-4Zr-4Mo-2Sn-1W-0.2Si duplex titanium alloys fabricated respectively via laser-directed energy deposition additive manufacturing (AM) and conventional forging technologies. The results revealed that the forged titanium alloy contained fine grains with a heterogeneously duplex structure consisting of large-size near-spherical primary α and hard β<sub>t</sub> phases. By contrast, the AMed titanium alloy contained columnar grains with an interior homogenous basketweave structure containing a few unstable high angle boundaries (HABs) and a high ratio of low angle boundaries (LABs). Although the room-temperature tensile strengths of two types of alloys were similar (∼1100 MPa), the AMed titanium alloy suggested superior high temperature mechanical properties with 8 % higher strength retention at 550 °C than the forged alloy (882 vs. 811 MPa). With an increase of total strain amplitude (Δ<em>ε<sub>t</sub></em>), the fatigue life of the specimen was prone to decreasing, associated with the declined texture intensity and activity of basal slip system of (0 0 0 1) [1 1 <span><math><mrow><mover><mrow><mn>2</mn></mrow><mrow><mo>¯</mo></mrow></mover><mspace></mspace></mrow></math></span>0]. Under the same Δ<em>ε<sub>t</sub></em> value of 0.6 %, the high temperature fatigue lives of the AMed alloys were 6–7 times longer than the forged counterparts. Fractographic analysis of the fatigue specimens revealed that surface slip cracking accompanied by oxide formation served as the predominant fatigue crack initiation mechanism, followed by striation patterns observed in crack propagation paths. Compared to the forged alloy, the higher fatigue properties of the AMed titanium alloy were mainly attributed to a higher thermostability and optimum microstructure design (fewer HABs and high ratio of LABs) resisting fatigue cracking. These findings offer a guide for the fabrication of next-generation titanium alloys requiring simultaneous high-temperature strength and fatigue resistance in aerospace applications.</div></div>\",\"PeriodicalId\":14112,\"journal\":{\"name\":\"International Journal of Fatigue\",\"volume\":\"201 \",\"pages\":\"Article 109195\"},\"PeriodicalIF\":6.8000,\"publicationDate\":\"2025-07-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Fatigue\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0142112325003925\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, MECHANICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Fatigue","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0142112325003925","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
Enhancing high-temperature fatigue resistance in duplex titanium alloys via process-tailored boundary engineering
The development of high-temperature titanium alloys for aerospace propulsion systems requires good thermostability and fatigue resistance under high temperature loading conditions. This study comparatively investigated the microstructural characteristics and fatigue performance of Ti-6Al-4Zr-4Mo-2Sn-1W-0.2Si duplex titanium alloys fabricated respectively via laser-directed energy deposition additive manufacturing (AM) and conventional forging technologies. The results revealed that the forged titanium alloy contained fine grains with a heterogeneously duplex structure consisting of large-size near-spherical primary α and hard βt phases. By contrast, the AMed titanium alloy contained columnar grains with an interior homogenous basketweave structure containing a few unstable high angle boundaries (HABs) and a high ratio of low angle boundaries (LABs). Although the room-temperature tensile strengths of two types of alloys were similar (∼1100 MPa), the AMed titanium alloy suggested superior high temperature mechanical properties with 8 % higher strength retention at 550 °C than the forged alloy (882 vs. 811 MPa). With an increase of total strain amplitude (Δεt), the fatigue life of the specimen was prone to decreasing, associated with the declined texture intensity and activity of basal slip system of (0 0 0 1) [1 1 0]. Under the same Δεt value of 0.6 %, the high temperature fatigue lives of the AMed alloys were 6–7 times longer than the forged counterparts. Fractographic analysis of the fatigue specimens revealed that surface slip cracking accompanied by oxide formation served as the predominant fatigue crack initiation mechanism, followed by striation patterns observed in crack propagation paths. Compared to the forged alloy, the higher fatigue properties of the AMed titanium alloy were mainly attributed to a higher thermostability and optimum microstructure design (fewer HABs and high ratio of LABs) resisting fatigue cracking. These findings offer a guide for the fabrication of next-generation titanium alloys requiring simultaneous high-temperature strength and fatigue resistance in aerospace applications.
期刊介绍:
Typical subjects discussed in International Journal of Fatigue address:
Novel fatigue testing and characterization methods (new kinds of fatigue tests, critical evaluation of existing methods, in situ measurement of fatigue degradation, non-contact field measurements)
Multiaxial fatigue and complex loading effects of materials and structures, exploring state-of-the-art concepts in degradation under cyclic loading
Fatigue in the very high cycle regime, including failure mode transitions from surface to subsurface, effects of surface treatment, processing, and loading conditions
Modeling (including degradation processes and related driving forces, multiscale/multi-resolution methods, computational hierarchical and concurrent methods for coupled component and material responses, novel methods for notch root analysis, fracture mechanics, damage mechanics, crack growth kinetics, life prediction and durability, and prediction of stochastic fatigue behavior reflecting microstructure and service conditions)
Models for early stages of fatigue crack formation and growth that explicitly consider microstructure and relevant materials science aspects
Understanding the influence or manufacturing and processing route on fatigue degradation, and embedding this understanding in more predictive schemes for mitigation and design against fatigue
Prognosis and damage state awareness (including sensors, monitoring, methodology, interactive control, accelerated methods, data interpretation)
Applications of technologies associated with fatigue and their implications for structural integrity and reliability. This includes issues related to design, operation and maintenance, i.e., life cycle engineering
Smart materials and structures that can sense and mitigate fatigue degradation
Fatigue of devices and structures at small scales, including effects of process route and surfaces/interfaces.