无过渡金属[3+2]环加成接入四唑：芳基唑砜的非自由基应用

IF 4.7 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2025-07-29 DOI:10.1039/d5qo00840a

Yulei Zhao, Ruiqing Wang, Xinyu Zong, Wenyi Chen, Xintian Zhang, Minghui Zhang

引用次数: 0

摘要

报道了芳偶氮砜与重氮化合物之间的无过渡金属[3+2]环加成反应。值得注意的是，芳偶氮砜表现出明显的反应性特征；相比之下，其他常见的偶氮化合物和芳基重氮盐在这种无过渡金属的条件下证明是无效的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Transition-Metal-Free [3+2] Cycloaddition to Access Tetrazoles: Non-radical Application of Arylazo Sulfones

A transition-metal-free [3+2] cycloaddition between arylazo sulfones and diazo compounds is reported. Notably, arylazo sulfones demonstrate distinct reactivity characteristics; in contrast, other common azo compounds and aryldiazonium salts prove ineffective under this transition-metal-free conditions.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.