Madeleine A. Ince, Steffen G. Hagemann, Nora A. Rubinstein, Marco L. Fiorentini, Anthony I.S. Kemp, Christopher M. Fisher, Tim Ireland, Santiago Gigola
{"title":"塔卡塔卡巴霍斑岩矿床岩浆来源与演化:对中安第斯古弧成矿作用和铜富性的启示","authors":"Madeleine A. Ince, Steffen G. Hagemann, Nora A. Rubinstein, Marco L. Fiorentini, Anthony I.S. Kemp, Christopher M. Fisher, Tim Ireland, Santiago Gigola","doi":"10.5382/econgeo.5169","DOIUrl":null,"url":null,"abstract":"The magmatic processes that lead to porphyry Cu ore formation in continental retro-arc environments are not well understood. As a result, the uncertainty of predictive exploration in these tectonic settings is elevated, and new case studies are needed to enhance the probability of success in target identification. The Taca Taca Bajo porphyry Cu-Mo-Au deposit is a well-mineralized (11.7 Mt contained Cu), retro-arc expression of the Middle Eocene to Early Oligocene metallogenic belt in the central Andes and represents a key location for investigating continental retro-arc magmatic processes that culminate in the formation of porphyry Cu deposits. Mineralization at Taca Taca Bajo is spatially and temporally correlated with a NE-SW–trending rhyodacitic porphyry dike swarm. Six samples of the mineralized Taca Taca Bajo rhyodacite porphyry and one of the barren west rhyodacite porphyry were analyzed for whole-rock geochemistry and zircon petrochronology (U-Pb geochronology, O isotopes, Lu-Hf isotopes, trace element geochemistry). The U-Pb SHRIMP analyses of zircons from the Taca Taca rhyodacite porphyry intrusions reveal ages ranging from 30.3 ± 0.5 Ma to 29.1 ± 0.3 Ma (95% confidence interval). The barren west rhyodacite porphyry sample yields an overlapping zircon crystallization age of 30.4 ± 0.4 Ma (U-Pb SHRIMP; 95% confidence interval) with mineralized samples. Whole-rock geochemistry reveals a subducted slab component to the magma, with enrichments in Ba and Th as well as a marked negative Nb and Ta anomaly. The mean zircon δ18O of both the barren and mineralized Oligocene intrusions ranges from 5.6 ± 0.5 to 5.8 ± 0.2‰ (2 standard deviations [SD]), and zircon εHf from 5.3 ± 2.4 to 7.6 ± 0.7 (2 SD). These similarities suggest that the mineralized and barren intrusions may have a relatively juvenile mantle-derived source with minor assimilation of older crust. Inherited zircons yield U-Pb ages of 48 to 1063 Ma, with a cluster at 230 to 280 Ma, indicative of interaction with older arc magmatic rocks of the lower Choiyoi Igneous Complex. The Taca Taca Oligocene intrusions are moderately hydrous (mean zircon Eu/Eu* = 0.25–0.34) and oxidized (mean ΔFMQ = 0.2–1.0 [FMQ = fayalite-magnetite-quartz]) as estimated from zircon-based proxies. However, they also have lower inferred H2O contents and fO2 than other Cu-porphyry deposits of the Eocene to Early Oligocene metallogenic belt (e.g., Escondida, Chuquicamata, El Salvador). Based on these data, it is possible to conclude that the Taca Taca Bajo deposit, despite being a large porphyry Cu deposit, may have failed to reach the scale of some others in the metallogenic belt because it experienced a relatively isolated, short (1–1.5 m.y.) magmatic pulse, and did not undergo the multimillion year build-up of magmatism characteristic of these major deposits.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"26 1","pages":""},"PeriodicalIF":4.9000,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Insights Into the Magma Source and Evolution of the Taca Taca Bajo Porphyry Deposit: Implications for the Metallogeny and Cu Fertility of the Central Andean Retro Arc\",\"authors\":\"Madeleine A. Ince, Steffen G. Hagemann, Nora A. Rubinstein, Marco L. Fiorentini, Anthony I.S. Kemp, Christopher M. Fisher, Tim Ireland, Santiago Gigola\",\"doi\":\"10.5382/econgeo.5169\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The magmatic processes that lead to porphyry Cu ore formation in continental retro-arc environments are not well understood. As a result, the uncertainty of predictive exploration in these tectonic settings is elevated, and new case studies are needed to enhance the probability of success in target identification. The Taca Taca Bajo porphyry Cu-Mo-Au deposit is a well-mineralized (11.7 Mt contained Cu), retro-arc expression of the Middle Eocene to Early Oligocene metallogenic belt in the central Andes and represents a key location for investigating continental retro-arc magmatic processes that culminate in the formation of porphyry Cu deposits. Mineralization at Taca Taca Bajo is spatially and temporally correlated with a NE-SW–trending rhyodacitic porphyry dike swarm. Six samples of the mineralized Taca Taca Bajo rhyodacite porphyry and one of the barren west rhyodacite porphyry were analyzed for whole-rock geochemistry and zircon petrochronology (U-Pb geochronology, O isotopes, Lu-Hf isotopes, trace element geochemistry). The U-Pb SHRIMP analyses of zircons from the Taca Taca rhyodacite porphyry intrusions reveal ages ranging from 30.3 ± 0.5 Ma to 29.1 ± 0.3 Ma (95% confidence interval). The barren west rhyodacite porphyry sample yields an overlapping zircon crystallization age of 30.4 ± 0.4 Ma (U-Pb SHRIMP; 95% confidence interval) with mineralized samples. Whole-rock geochemistry reveals a subducted slab component to the magma, with enrichments in Ba and Th as well as a marked negative Nb and Ta anomaly. The mean zircon δ18O of both the barren and mineralized Oligocene intrusions ranges from 5.6 ± 0.5 to 5.8 ± 0.2‰ (2 standard deviations [SD]), and zircon εHf from 5.3 ± 2.4 to 7.6 ± 0.7 (2 SD). These similarities suggest that the mineralized and barren intrusions may have a relatively juvenile mantle-derived source with minor assimilation of older crust. Inherited zircons yield U-Pb ages of 48 to 1063 Ma, with a cluster at 230 to 280 Ma, indicative of interaction with older arc magmatic rocks of the lower Choiyoi Igneous Complex. The Taca Taca Oligocene intrusions are moderately hydrous (mean zircon Eu/Eu* = 0.25–0.34) and oxidized (mean ΔFMQ = 0.2–1.0 [FMQ = fayalite-magnetite-quartz]) as estimated from zircon-based proxies. However, they also have lower inferred H2O contents and fO2 than other Cu-porphyry deposits of the Eocene to Early Oligocene metallogenic belt (e.g., Escondida, Chuquicamata, El Salvador). Based on these data, it is possible to conclude that the Taca Taca Bajo deposit, despite being a large porphyry Cu deposit, may have failed to reach the scale of some others in the metallogenic belt because it experienced a relatively isolated, short (1–1.5 m.y.) magmatic pulse, and did not undergo the multimillion year build-up of magmatism characteristic of these major deposits.\",\"PeriodicalId\":11469,\"journal\":{\"name\":\"Economic Geology\",\"volume\":\"26 1\",\"pages\":\"\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2025-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Economic Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://doi.org/10.5382/econgeo.5169\",\"RegionNum\":1,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Economic Geology","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.5382/econgeo.5169","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Insights Into the Magma Source and Evolution of the Taca Taca Bajo Porphyry Deposit: Implications for the Metallogeny and Cu Fertility of the Central Andean Retro Arc
The magmatic processes that lead to porphyry Cu ore formation in continental retro-arc environments are not well understood. As a result, the uncertainty of predictive exploration in these tectonic settings is elevated, and new case studies are needed to enhance the probability of success in target identification. The Taca Taca Bajo porphyry Cu-Mo-Au deposit is a well-mineralized (11.7 Mt contained Cu), retro-arc expression of the Middle Eocene to Early Oligocene metallogenic belt in the central Andes and represents a key location for investigating continental retro-arc magmatic processes that culminate in the formation of porphyry Cu deposits. Mineralization at Taca Taca Bajo is spatially and temporally correlated with a NE-SW–trending rhyodacitic porphyry dike swarm. Six samples of the mineralized Taca Taca Bajo rhyodacite porphyry and one of the barren west rhyodacite porphyry were analyzed for whole-rock geochemistry and zircon petrochronology (U-Pb geochronology, O isotopes, Lu-Hf isotopes, trace element geochemistry). The U-Pb SHRIMP analyses of zircons from the Taca Taca rhyodacite porphyry intrusions reveal ages ranging from 30.3 ± 0.5 Ma to 29.1 ± 0.3 Ma (95% confidence interval). The barren west rhyodacite porphyry sample yields an overlapping zircon crystallization age of 30.4 ± 0.4 Ma (U-Pb SHRIMP; 95% confidence interval) with mineralized samples. Whole-rock geochemistry reveals a subducted slab component to the magma, with enrichments in Ba and Th as well as a marked negative Nb and Ta anomaly. The mean zircon δ18O of both the barren and mineralized Oligocene intrusions ranges from 5.6 ± 0.5 to 5.8 ± 0.2‰ (2 standard deviations [SD]), and zircon εHf from 5.3 ± 2.4 to 7.6 ± 0.7 (2 SD). These similarities suggest that the mineralized and barren intrusions may have a relatively juvenile mantle-derived source with minor assimilation of older crust. Inherited zircons yield U-Pb ages of 48 to 1063 Ma, with a cluster at 230 to 280 Ma, indicative of interaction with older arc magmatic rocks of the lower Choiyoi Igneous Complex. The Taca Taca Oligocene intrusions are moderately hydrous (mean zircon Eu/Eu* = 0.25–0.34) and oxidized (mean ΔFMQ = 0.2–1.0 [FMQ = fayalite-magnetite-quartz]) as estimated from zircon-based proxies. However, they also have lower inferred H2O contents and fO2 than other Cu-porphyry deposits of the Eocene to Early Oligocene metallogenic belt (e.g., Escondida, Chuquicamata, El Salvador). Based on these data, it is possible to conclude that the Taca Taca Bajo deposit, despite being a large porphyry Cu deposit, may have failed to reach the scale of some others in the metallogenic belt because it experienced a relatively isolated, short (1–1.5 m.y.) magmatic pulse, and did not undergo the multimillion year build-up of magmatism characteristic of these major deposits.
期刊介绍:
The journal, now published semi-quarterly, was first published in 1905 by the Economic Geology Publishing Company (PUBCO), a not-for-profit company established for the purpose of publishing a periodical devoted to economic geology. On the founding of SEG in 1920, a cooperative arrangement between PUBCO and SEG made the journal the official organ of the Society, and PUBCO agreed to carry the Society''s name on the front cover under the heading "Bulletin of the Society of Economic Geologists". PUBCO and SEG continued to operate as cooperating but separate entities until 2001, when the Board of Directors of PUBCO and the Council of SEG, by unanimous consent, approved a formal agreement of merger. The former activities of the PUBCO Board of Directors are now carried out by a Publications Board, a new self-governing unit within SEG.