新型介孔牛磺酸掺杂聚苯胺/聚乙烯醇静电纺复合纳米纤维的综合研究

M.S. Archana , C.S. Chitra Lekha , S. Deepa , Nandakumar Kalarikkal
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引用次数: 0

摘要

导电性聚合物,特别是聚苯胺(PANI),由于其独特的导电性、柔韧性和可调特性的组合而受到广泛关注,这使其成为储能、传感器和柔性电子产品应用的理想选择。然而,聚苯胺有限的机械性能,较差的可加工性,以及在生理环境中的电导率损失使其不适合实际应用。为了克服这些问题,聚苯胺经常被加入到聚合物复合材料中。为了改善聚苯胺的性能,将生物相容性氨基酸牛磺酸(Tau)掺入聚苯胺中,采用静电纺丝法制备了t -聚苯胺/聚乙烯醇复合纳米纤维。牛磺酸作为一种高效的生物活性掺杂剂,与其磺酸基团一起改善聚苯胺的导电性和生物相容性。x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、场发射扫描电子显微镜(FESEM)、布鲁诺尔-埃米特-泰勒(BET)表面积分析、紫外-可见光谱、光致发光(PL)光谱、热重分析(TGA)和力学研究等方法对静电纺(T- PANI/PVA)复合纤维进行了系统表征。研究结果表明,掺入牛磺酸增强了纳米纤维的机械稳定性、电导率和热特性,同时改善了离子传输和分子排列。这些结果表明,牛磺酸掺杂的聚苯胺/聚乙烯醇纳米纤维具有聚苯胺的导电性能、聚乙烯醇的机械强度和牛磺酸的生物相容性,为柔性电子、传感器和生物医学应用提供了一个潜在的平台。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A Novel Mesoporous Taurine-Doped Polyaniline/PVA Electrospun Composite Nanofiber: Comprehensive Study

A Novel Mesoporous Taurine-Doped Polyaniline/PVA Electrospun Composite Nanofiber: Comprehensive Study
Conductive polymers, in particular polyaniline (PANI), are gaining a lot of attention because of their unique combination of electrical conductivity, flexibility, and tunable properties, which make them ideal for applications in energy storage, sensors, and flexible electronics. However, PANI's limited mechanical properties, poor machinability, and conductivity loss in physiological environments make them unsuitable for practical use. To overcome these problems, PANI is frequently incorporated into polymer composites. In order to improve PANI's properties, taurine (Tau), a biocompatible amino acid, is doped into PANI, and T-PANI/PVA composite nanofibers are made by electrospinning. Taurine improves PANI's conductivity and biocompatibility by acting as an efficient bioactive dopant with its sulfonic acid group. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), Brunauer–Emmett–Teller (BET) surface area analysis, UV–visible spectroscopy, photoluminescence (PL) spectroscopy, Thermogravimetric analysis (TGA) and mechanical studies were among the methods used to systematically characterize the electrospun (T- PANI/PVA) composite fibers. According to the findings, taurine doping enhances the nanofibers' mechanical stability, electrical conductivity, and thermal characteristics along with improved ion transport and molecular alignment. These results imply that taurine-doped PANI/PVA nanofibers, equipped with the conductive qualities of PANI, mechanical strength of PVA and the biocompatibility of taurine, provide a potential platform for flexible electronics, sensors, and biomedical applications.
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