{"title":"不同直径混合金纳米颗粒制备致密薄膜的表面增强拉曼散射特性。","authors":"Natsuki Koyama, Hironobu Tahara, Takeo Oku, Tsuyoshi Akiyama","doi":"10.1002/cphc.202500250","DOIUrl":null,"url":null,"abstract":"<p>Densely-packed thin films of plasmonic nanoparticles enhance Raman scattering. The effect of size uniformity of plasmonic nanoparticles in such thin films contributes to the development of highly sensitive Raman scattering spectroscopy for practical use. In this research, densely-packed thin films containing a mixture of gold nanoparticles with two different sizes are fabricated and evaluated about their surface-enhanced Raman scattering properties. The enhancement efficiency of gold nanoparticle films with different sizes is lower than that of single-sized gold nanoparticle films. This tendency suggests a relationship between Raman scattering enhancement efficiency and the electric field generated by localized surface plasmon resonance among gold nanoparticles of different sizes.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":"26 17","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Surface-Enhanced Raman Scattering Properties of Densely-Packed Thin-Films Fabricated using Mixed Gold Nanoparticles with Different Diameters\",\"authors\":\"Natsuki Koyama, Hironobu Tahara, Takeo Oku, Tsuyoshi Akiyama\",\"doi\":\"10.1002/cphc.202500250\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Densely-packed thin films of plasmonic nanoparticles enhance Raman scattering. The effect of size uniformity of plasmonic nanoparticles in such thin films contributes to the development of highly sensitive Raman scattering spectroscopy for practical use. In this research, densely-packed thin films containing a mixture of gold nanoparticles with two different sizes are fabricated and evaluated about their surface-enhanced Raman scattering properties. The enhancement efficiency of gold nanoparticle films with different sizes is lower than that of single-sized gold nanoparticle films. This tendency suggests a relationship between Raman scattering enhancement efficiency and the electric field generated by localized surface plasmon resonance among gold nanoparticles of different sizes.</p>\",\"PeriodicalId\":9819,\"journal\":{\"name\":\"Chemphyschem\",\"volume\":\"26 17\",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2025-07-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemphyschem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cphc.202500250\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemphyschem","FirstCategoryId":"92","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cphc.202500250","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Surface-Enhanced Raman Scattering Properties of Densely-Packed Thin-Films Fabricated using Mixed Gold Nanoparticles with Different Diameters
Densely-packed thin films of plasmonic nanoparticles enhance Raman scattering. The effect of size uniformity of plasmonic nanoparticles in such thin films contributes to the development of highly sensitive Raman scattering spectroscopy for practical use. In this research, densely-packed thin films containing a mixture of gold nanoparticles with two different sizes are fabricated and evaluated about their surface-enhanced Raman scattering properties. The enhancement efficiency of gold nanoparticle films with different sizes is lower than that of single-sized gold nanoparticle films. This tendency suggests a relationship between Raman scattering enhancement efficiency and the electric field generated by localized surface plasmon resonance among gold nanoparticles of different sizes.
期刊介绍：
ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.
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