David Maya-Franco, Emmanuel Martínez-Guerrero, Guo-Hua Sun, Shi-Hai Dong
{"title":"分数阶Schrödinger框架下双双曲势量子信息熵的探索","authors":"David Maya-Franco, Emmanuel Martínez-Guerrero, Guo-Hua Sun, Shi-Hai Dong","doi":"10.1002/qua.70086","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>In this work, we investigate quantum information entropy for double hyperbolic well potentials within the framework of the fractional Schrödinger equation (FSE). Specifically, we analyze the position and momentum Shannon entropies for two hyperbolic potentials, <span></span><math>\n <semantics>\n <mrow>\n <msub>\n <mrow>\n <mi>U</mi>\n </mrow>\n <mrow>\n <mn>1</mn>\n </mrow>\n </msub>\n </mrow>\n <annotation>$$ {U}_1 $$</annotation>\n </semantics></math> and <span></span><math>\n <semantics>\n <mrow>\n <msub>\n <mrow>\n <mi>U</mi>\n </mrow>\n <mrow>\n <mn>2</mn>\n </mrow>\n </msub>\n </mrow>\n <annotation>$$ {U}_2 $$</annotation>\n </semantics></math>, as a function of the fractional derivative order <span></span><math>\n <semantics>\n <mrow>\n <mi>μ</mi>\n </mrow>\n <annotation>$$ \\mu $$</annotation>\n </semantics></math>. Our findings reveal that decreasing <span></span><math>\n <semantics>\n <mrow>\n <mi>μ</mi>\n </mrow>\n <annotation>$$ \\mu $$</annotation>\n </semantics></math> enhances wave function localization in position space, thereby reducing spatial uncertainty while simultaneously increasing momentum uncertainty. We confirm the validity of the Beckner–Bialynicki-Birula–Mycielski inequality for both potentials, demonstrating its robustness across different degrees of nonlocality. Furthermore, we explore the behavior of Fisher information, observing that it increases in position space while decreases in momentum space as the well depths grow.</p>\n </div>","PeriodicalId":182,"journal":{"name":"International Journal of Quantum Chemistry","volume":"125 15","pages":""},"PeriodicalIF":2.0000,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Exploring Quantum Information Entropy in Double Hyperbolic Potentials Under the Fractional Schrödinger Framework\",\"authors\":\"David Maya-Franco, Emmanuel Martínez-Guerrero, Guo-Hua Sun, Shi-Hai Dong\",\"doi\":\"10.1002/qua.70086\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>In this work, we investigate quantum information entropy for double hyperbolic well potentials within the framework of the fractional Schrödinger equation (FSE). Specifically, we analyze the position and momentum Shannon entropies for two hyperbolic potentials, <span></span><math>\\n <semantics>\\n <mrow>\\n <msub>\\n <mrow>\\n <mi>U</mi>\\n </mrow>\\n <mrow>\\n <mn>1</mn>\\n </mrow>\\n </msub>\\n </mrow>\\n <annotation>$$ {U}_1 $$</annotation>\\n </semantics></math> and <span></span><math>\\n <semantics>\\n <mrow>\\n <msub>\\n <mrow>\\n <mi>U</mi>\\n </mrow>\\n <mrow>\\n <mn>2</mn>\\n </mrow>\\n </msub>\\n </mrow>\\n <annotation>$$ {U}_2 $$</annotation>\\n </semantics></math>, as a function of the fractional derivative order <span></span><math>\\n <semantics>\\n <mrow>\\n <mi>μ</mi>\\n </mrow>\\n <annotation>$$ \\\\mu $$</annotation>\\n </semantics></math>. Our findings reveal that decreasing <span></span><math>\\n <semantics>\\n <mrow>\\n <mi>μ</mi>\\n </mrow>\\n <annotation>$$ \\\\mu $$</annotation>\\n </semantics></math> enhances wave function localization in position space, thereby reducing spatial uncertainty while simultaneously increasing momentum uncertainty. We confirm the validity of the Beckner–Bialynicki-Birula–Mycielski inequality for both potentials, demonstrating its robustness across different degrees of nonlocality. Furthermore, we explore the behavior of Fisher information, observing that it increases in position space while decreases in momentum space as the well depths grow.</p>\\n </div>\",\"PeriodicalId\":182,\"journal\":{\"name\":\"International Journal of Quantum Chemistry\",\"volume\":\"125 15\",\"pages\":\"\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2025-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Quantum Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/qua.70086\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Quantum Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/qua.70086","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Exploring Quantum Information Entropy in Double Hyperbolic Potentials Under the Fractional Schrödinger Framework
In this work, we investigate quantum information entropy for double hyperbolic well potentials within the framework of the fractional Schrödinger equation (FSE). Specifically, we analyze the position and momentum Shannon entropies for two hyperbolic potentials, and , as a function of the fractional derivative order . Our findings reveal that decreasing enhances wave function localization in position space, thereby reducing spatial uncertainty while simultaneously increasing momentum uncertainty. We confirm the validity of the Beckner–Bialynicki-Birula–Mycielski inequality for both potentials, demonstrating its robustness across different degrees of nonlocality. Furthermore, we explore the behavior of Fisher information, observing that it increases in position space while decreases in momentum space as the well depths grow.
期刊介绍:
Since its first formulation quantum chemistry has provided the conceptual and terminological framework necessary to understand atoms, molecules and the condensed matter. Over the past decades synergistic advances in the methodological developments, software and hardware have transformed quantum chemistry in a truly interdisciplinary science that has expanded beyond its traditional core of molecular sciences to fields as diverse as chemistry and catalysis, biophysics, nanotechnology and material science.