铑催化氧化亚氮加氢†

IF 4.2 3区化学 Q2 CHEMISTRY, PHYSICAL

Catalysis Science & Technology Pub Date : 2025-05-16 DOI:10.1039/d5cy00490j

Sophie H. Dewick , Thomas M. Hood , Yisong Han , Steven Huband , Adrian B. Chaplin

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引用次数: 0

摘要

我们报道了在氧化亚氮加氢过程中发现的“隐藏”多相催化，同时评估了由名义上健壮的磷化氢螯配体支持的铑(I)氢化物配合物的催化活性。市售的[Rh(COD)(OH)]2随后被确定为一种更有效的催化剂前驱体，能够在室温下以3000的表观周转数加氢氧化亚氮。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Rhodium-catalysed hydrogenation of nitrous oxide†

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Rhodium-catalysed hydrogenation of nitrous oxide†

We report on the discovery of “hidden” heterogeneous catalysis in the hydrogenation of nitrous oxide while assessing the catalytic activity of a rhodium(i) hydride complex supported by a nominally robust phosphine-based pincer ligand. Commercially available [Rh(COD)(OH)]₂ was subsequently identified as a more effective catalyst precursor, enabling the hydrogenation of nitrous oxide with an apparent turnover number >3000 at room temeprature.

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来源期刊

Catalysis Science & Technology CHEMISTRY, PHYSICAL-

CiteScore

8.70

自引率

6.00%

发文量

587

审稿时长

1.5 months

期刊介绍： A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days