交替供体-受体碳纳米环：合成、光物理和超分子性质。

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-07-09 DOI:10.1021/acs.orglett.5c02463

Bing Yuan, Jinyi Wang, Xinyu Zhang, Pengwei Fang, Nan Yin and Pingwu Du*,

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引用次数: 0

摘要

在此，我们报道了基于二吡咯烷硼（BODIPY）的交替供体-受体（D-A）碳纳米环BCN-1和BCN-2。这些D-A纳米环具有窄的HOMO-LUMO间隙，高摩尔消光系数，宽可见区吸收和溶剂变色。DFT计算表明，BCN-2具有与[13]CPP相当的空腔大小，使其成为嵌套[8]CPP的合适宿主，形成具有高结合常数的二元配合物，表现出强烈的主客体相互作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Alternating Donor–Acceptor Carbon Nanohoops: Synthesis and Photophysical and Supramolecular Properties

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Alternating Donor–Acceptor Carbon Nanohoops: Synthesis and Photophysical and Supramolecular Properties

Herein, we report alternating boron dipyrromethene (BODIPY)-based donor-acceptor (D–A) carbon nanohoops, BCN-1 and BCN-2. These D–A nanohoops exhibit a narrow HOMO–LUMO gap, high molar extinction coefficients, broad visible-region absorption, and solvatochromism. DFT calculations reveal that BCN-2 possesses a cavity size comparable to that of [13]CPP, making it a suitable host for nesting [8]CPP to form a binary complex with a high binding constant, demonstrating strong host–guest interactions.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.