Owais Ahsan , Hira Ehsan , Fatima Tahir , Sohail Nadeem , Mobeen Murtaza , Muhammad Shahzad Kmal , Muhammad Azeem Akbar Rana , Hafiza Tanawish Habib , Ali Bahadur , Shahid Iqbal , Sajid Mahmood , Syed Kashif Ali , Shaimaa A.M. Abdelmohsen , Randa A. Althobiti
{"title":"掺钒钼铁氧体NPs/S-g-C3N4光催化降解染料复合材料的制备及应用","authors":"Owais Ahsan , Hira Ehsan , Fatima Tahir , Sohail Nadeem , Mobeen Murtaza , Muhammad Shahzad Kmal , Muhammad Azeem Akbar Rana , Hafiza Tanawish Habib , Ali Bahadur , Shahid Iqbal , Sajid Mahmood , Syed Kashif Ali , Shaimaa A.M. Abdelmohsen , Randa A. Althobiti","doi":"10.1016/j.poly.2025.117662","DOIUrl":null,"url":null,"abstract":"<div><div>This investigation looks at the way sulfur-doped graphitic carbon nitride (S-g-C<sub>3</sub>N<sub>4</sub>) and vanadium-doped iron molybdate (<em>V</em>-MoFe<sub>2</sub>O<sub>4</sub>) nanocomposites are prepared and tested for their effect on environmental protection. To produce S-g-C<sub>3</sub>N<sub>4</sub>, a solvothermal method was used and <em>V</em>-MoFe<sub>2</sub>O<sub>4</sub> nanoparticles were made using a hydrothermal approach by doping vanadium at differing amounts (2, 4, 6, 8 and 10 mol%). The methylene blue (MB) dye was tested under sunlight to evaluate photocatalytic activity. <em>V</em>-MoFe<sub>2</sub>O<sub>4</sub> with an 8 mol% amount of V achieved the maximum degradation efficiency in all the samples. Nanocomposites with certain contents of S-g-C<sub>3</sub>N<sub>4</sub> (including 10 %, 50 %, 70 % and 90 %) and 8 % of V-MoFe<sub>2</sub>O<sub>4</sub> formulations were made to increase activity. The S-g-C<sub>3</sub>N<sub>4</sub>/<em>V</em>-MoFe<sub>2</sub>O<sub>4</sub> composite (90 % S-g-C<sub>3</sub>N<sub>4</sub> + 8 % V-MoFe<sub>2</sub>O<sub>4</sub>) did the best job of removing dyes in a little over two hours. Through X-ray diffraction (XRD), FTIR, scanning electron microscopy (SEM) and U<em>V</em>–visible spectroscopy, we showed that the nanocomposites formed correctly and had good structural features. According to these findings, the S-g-C<sub>3</sub>N<sub>4</sub>/V-MoFe<sub>2</sub>O<sub>4</sub> combination could be a good choice for treating wastewater using solar power.</div></div>","PeriodicalId":20278,"journal":{"name":"Polyhedron","volume":"279 ","pages":"Article 117662"},"PeriodicalIF":2.4000,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabricating and applications of vanadium doped molybdenum ferrites NPs/S-g-C3N4 composites for photocatalytic degradation of dyes\",\"authors\":\"Owais Ahsan , Hira Ehsan , Fatima Tahir , Sohail Nadeem , Mobeen Murtaza , Muhammad Shahzad Kmal , Muhammad Azeem Akbar Rana , Hafiza Tanawish Habib , Ali Bahadur , Shahid Iqbal , Sajid Mahmood , Syed Kashif Ali , Shaimaa A.M. Abdelmohsen , Randa A. Althobiti\",\"doi\":\"10.1016/j.poly.2025.117662\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This investigation looks at the way sulfur-doped graphitic carbon nitride (S-g-C<sub>3</sub>N<sub>4</sub>) and vanadium-doped iron molybdate (<em>V</em>-MoFe<sub>2</sub>O<sub>4</sub>) nanocomposites are prepared and tested for their effect on environmental protection. To produce S-g-C<sub>3</sub>N<sub>4</sub>, a solvothermal method was used and <em>V</em>-MoFe<sub>2</sub>O<sub>4</sub> nanoparticles were made using a hydrothermal approach by doping vanadium at differing amounts (2, 4, 6, 8 and 10 mol%). The methylene blue (MB) dye was tested under sunlight to evaluate photocatalytic activity. <em>V</em>-MoFe<sub>2</sub>O<sub>4</sub> with an 8 mol% amount of V achieved the maximum degradation efficiency in all the samples. Nanocomposites with certain contents of S-g-C<sub>3</sub>N<sub>4</sub> (including 10 %, 50 %, 70 % and 90 %) and 8 % of V-MoFe<sub>2</sub>O<sub>4</sub> formulations were made to increase activity. The S-g-C<sub>3</sub>N<sub>4</sub>/<em>V</em>-MoFe<sub>2</sub>O<sub>4</sub> composite (90 % S-g-C<sub>3</sub>N<sub>4</sub> + 8 % V-MoFe<sub>2</sub>O<sub>4</sub>) did the best job of removing dyes in a little over two hours. Through X-ray diffraction (XRD), FTIR, scanning electron microscopy (SEM) and U<em>V</em>–visible spectroscopy, we showed that the nanocomposites formed correctly and had good structural features. 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Fabricating and applications of vanadium doped molybdenum ferrites NPs/S-g-C3N4 composites for photocatalytic degradation of dyes
This investigation looks at the way sulfur-doped graphitic carbon nitride (S-g-C3N4) and vanadium-doped iron molybdate (V-MoFe2O4) nanocomposites are prepared and tested for their effect on environmental protection. To produce S-g-C3N4, a solvothermal method was used and V-MoFe2O4 nanoparticles were made using a hydrothermal approach by doping vanadium at differing amounts (2, 4, 6, 8 and 10 mol%). The methylene blue (MB) dye was tested under sunlight to evaluate photocatalytic activity. V-MoFe2O4 with an 8 mol% amount of V achieved the maximum degradation efficiency in all the samples. Nanocomposites with certain contents of S-g-C3N4 (including 10 %, 50 %, 70 % and 90 %) and 8 % of V-MoFe2O4 formulations were made to increase activity. The S-g-C3N4/V-MoFe2O4 composite (90 % S-g-C3N4 + 8 % V-MoFe2O4) did the best job of removing dyes in a little over two hours. Through X-ray diffraction (XRD), FTIR, scanning electron microscopy (SEM) and UV–visible spectroscopy, we showed that the nanocomposites formed correctly and had good structural features. According to these findings, the S-g-C3N4/V-MoFe2O4 combination could be a good choice for treating wastewater using solar power.
期刊介绍:
Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry.
Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.