基于微生物诱导碳酸盐沉淀(MICP)的金尾矿固化大规模研究

Yaoting Duan , Qin Yuan , Caiqi Yu , Chunli Zheng
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引用次数: 0

摘要

微生物诱导碳酸盐沉淀(MICP)的应用面临的主要挑战之一是实现“无细菌”,因为它需要大量的细菌溶液。然而,原位细菌培养和细菌溶液的运输都被证明是低效的。在本研究中,我们建议以干粉的形式利用细菌,便于现场激活,并获得相对较高的脲酶活性。以钢渣(SS)为添加剂,对金尾矿(GMT)进行了MICP固化试验。结果表明:经MICP和MICP+SS处理的尾矿平均无侧限抗压强度(UCS)分别达到0.51和0.71 MPa;MICP处理后GMT中Cu、Pb、Cr、Zn、T-CN的平均浸出还原率分别为98.54%、100%、70.94%、59.25%、98.02%,MICP+SS处理后的平均还原率分别为98.77%、100%、88.03%、72.59%、98.63%。SEM、XRD、FT-IR、超深场显微镜等分析结果证实,MICP处理产生的方解石基碳酸钙填充尾砂间孔隙并胶结在一起,水化机制是提高SS固化效率的主要原因。研究结果表明,细菌粉可以有效地达到去除重金属和尾砂固化的目的。该方法可以大大减少细菌培养和溶液运输的相关费用,从而在推进MICP的实际实施中发挥关键作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A large-scale study on solidification of gold tailings based on microbially induced carbonate precipitation (MICP)
One of the major challenges in the application of microbially induced carbonate precipitation (MICP) is achieving "bacteria freedom", as it necessitates a substantial volume of bacterial solutions. Nevertheless, both in-situ bacterial cultivation and transportation of bacterial solutions have proven to be inefficient. In this study, we suggested the utilization of bacteria in the form of dry powder, enabling easy on-site activation and achieving a relatively high urease activity. We conducted MICP curing experiments on gold mine tailings (GMT) using steel slag (SS) as an additive. The results showed that the average unconfined compressive strength (UCS) values of the tailings treated with MICP and MICP+SS reached 0.51 and 0.71 MPa, respectively. In addition, the average leaching reduction rates of Cu, Pb, Cr, Zn, and T-CN in GMT after MICP treatment reached 98.54%, 100%, 70.94%, 59.25%, and 98.02%, respectively, and the average reduction rates after MICP+SS treatment reached 98.77%, 100%, 88.03%, 72.59%, and 98.63%, respectively. SEM, XRD, FT-IR analyses, and ultra-deep field microscopy results confirmed that the MICP treatment produced calcite-based calcium carbonate that filled the inter-tailing pores and cemented them together, and the hydration mechanism was the main reason for the increased curing efficiency of SS. Our research findings demonstrate that bacterial powder can efficiently achieve the objectives of heavy metal removal and tailing solidification. This approach can substantially decrease the expenses associated with bacterial cultivation and solution transportation, thereby playing a crucial role in advancing the practical implementation of MICP.
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