Dawid Marcinkowski, Dominika Prętka, Przemysław Woźny, Jedrzej Kobylarczyk, Agnieszka Siwiak, Dawid Pakulski, Violetta Patroniak, Kinga Roszak, Andrzej Katrusiak, Radovan Herchel, Robert Podgajny, Szymon Sobczak, Natalia Majewska, Sebastian Mahlik, Marcin Runowski, Adam Gorczyński
{"title":"磁慢弛豫Nd(III)基非温度压力计和非压力温度计","authors":"Dawid Marcinkowski, Dominika Prętka, Przemysław Woźny, Jedrzej Kobylarczyk, Agnieszka Siwiak, Dawid Pakulski, Violetta Patroniak, Kinga Roszak, Andrzej Katrusiak, Radovan Herchel, Robert Podgajny, Szymon Sobczak, Natalia Majewska, Sebastian Mahlik, Marcin Runowski, Adam Gorczyński","doi":"10.1002/adom.202500495","DOIUrl":null,"url":null,"abstract":"<p>\nImplementing multifunctional characteristics in a metallo-supramolecular system with reversible stimuli-induced response is a significant challenge. In this study, a simple, readily available macrocyclic Nd(III) complex [Nd<b>L</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>3</sub>] (<b>1</b>) exhibits tunable emission from the lanthanide center, which can be modulated by temperature and pressure. Within phase α at 1.5 GPa the onset of negative linear compressibility (NLC) along axis a takes place. At 3.0 GPa, single-crystal X-ray diffraction reveals the CF<sub>3</sub>SO<sub>3</sub>\n <sup>−</sup> ion ordering, inducing a non-centrosymmetric phase β with modified material properties. Phase α shows strong pressure-induced absorption and emission changes, suitable for precise, temperature-independent luminescent manometry, with an emission line shift of Δ<i>λ</i>/Δ<i>p</i> = 2.85 nm GPa<sup>−1</sup> in the NIR range. The designed optical sensor also enables remote temperature monitoring (15–460 K) through a pressure-independent band intensity ratio of Nd(III) Stark components. Finally, field-induced slow relaxation of magnetization is observed and analyzed using both standard fitting procedures and alternative approach that accounts for the influence of local vibration modes. This unique coexistence of these behaviors mark a significant step toward creating multifunctional supramolecular platforms, easily extendable to other systems with tunable properties.</p>","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 19","pages":""},"PeriodicalIF":7.2000,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adom.202500495","citationCount":"0","resultStr":"{\"title\":\"Nd(III)-Based Temperature-Independent Manometer and Pressure-Independent Thermometer with Slow Relaxation of Magnetization\",\"authors\":\"Dawid Marcinkowski, Dominika Prętka, Przemysław Woźny, Jedrzej Kobylarczyk, Agnieszka Siwiak, Dawid Pakulski, Violetta Patroniak, Kinga Roszak, Andrzej Katrusiak, Radovan Herchel, Robert Podgajny, Szymon Sobczak, Natalia Majewska, Sebastian Mahlik, Marcin Runowski, Adam Gorczyński\",\"doi\":\"10.1002/adom.202500495\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>\\nImplementing multifunctional characteristics in a metallo-supramolecular system with reversible stimuli-induced response is a significant challenge. In this study, a simple, readily available macrocyclic Nd(III) complex [Nd<b>L</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>3</sub>] (<b>1</b>) exhibits tunable emission from the lanthanide center, which can be modulated by temperature and pressure. Within phase α at 1.5 GPa the onset of negative linear compressibility (NLC) along axis a takes place. At 3.0 GPa, single-crystal X-ray diffraction reveals the CF<sub>3</sub>SO<sub>3</sub>\\n <sup>−</sup> ion ordering, inducing a non-centrosymmetric phase β with modified material properties. Phase α shows strong pressure-induced absorption and emission changes, suitable for precise, temperature-independent luminescent manometry, with an emission line shift of Δ<i>λ</i>/Δ<i>p</i> = 2.85 nm GPa<sup>−1</sup> in the NIR range. The designed optical sensor also enables remote temperature monitoring (15–460 K) through a pressure-independent band intensity ratio of Nd(III) Stark components. Finally, field-induced slow relaxation of magnetization is observed and analyzed using both standard fitting procedures and alternative approach that accounts for the influence of local vibration modes. This unique coexistence of these behaviors mark a significant step toward creating multifunctional supramolecular platforms, easily extendable to other systems with tunable properties.</p>\",\"PeriodicalId\":116,\"journal\":{\"name\":\"Advanced Optical Materials\",\"volume\":\"13 19\",\"pages\":\"\"},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2025-06-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adom.202500495\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Optical Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adom.202500495\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adom.202500495","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Nd(III)-Based Temperature-Independent Manometer and Pressure-Independent Thermometer with Slow Relaxation of Magnetization
Implementing multifunctional characteristics in a metallo-supramolecular system with reversible stimuli-induced response is a significant challenge. In this study, a simple, readily available macrocyclic Nd(III) complex [NdL(CF3SO3)3] (1) exhibits tunable emission from the lanthanide center, which can be modulated by temperature and pressure. Within phase α at 1.5 GPa the onset of negative linear compressibility (NLC) along axis a takes place. At 3.0 GPa, single-crystal X-ray diffraction reveals the CF3SO3− ion ordering, inducing a non-centrosymmetric phase β with modified material properties. Phase α shows strong pressure-induced absorption and emission changes, suitable for precise, temperature-independent luminescent manometry, with an emission line shift of Δλ/Δp = 2.85 nm GPa−1 in the NIR range. The designed optical sensor also enables remote temperature monitoring (15–460 K) through a pressure-independent band intensity ratio of Nd(III) Stark components. Finally, field-induced slow relaxation of magnetization is observed and analyzed using both standard fitting procedures and alternative approach that accounts for the influence of local vibration modes. This unique coexistence of these behaviors mark a significant step toward creating multifunctional supramolecular platforms, easily extendable to other systems with tunable properties.
期刊介绍:
Advanced Optical Materials, part of the esteemed Advanced portfolio, is a unique materials science journal concentrating on all facets of light-matter interactions. For over a decade, it has been the preferred optical materials journal for significant discoveries in photonics, plasmonics, metamaterials, and more. The Advanced portfolio from Wiley is a collection of globally respected, high-impact journals that disseminate the best science from established and emerging researchers, aiding them in fulfilling their mission and amplifying the reach of their scientific discoveries.