Oskar Chmel, Ondřej Jankovský, Tomáš Hlásek, Michal Lojka, David Sedmidubský, Petra Šimonová, Filip Antončík
{"title":"高效集成Gd-2411-W人工钉钉在单方向熔体生长的大量GdBCO/Ag块中","authors":"Oskar Chmel, Ondřej Jankovský, Tomáš Hlásek, Michal Lojka, David Sedmidubský, Petra Šimonová, Filip Antončík","doi":"10.1111/jace.20678","DOIUrl":null,"url":null,"abstract":"<p>To increase the application potential of superconducting materials, their key properties, such as critical current density, trapped field, and overall homogeneity, must be improved. It is long established that these properties can be enhanced by pinning phase addition. However, the innate fragility of top-seeded melt growth has prohibited a substantial amount of pinning from being added to bulks grown by top-seeded melt growth. Due to its robustness, the newly developed single-direction melt growth (SDMG) method should allow the integration of significantly higher mass concentrations into the superconducting matrix. For the GdBCO/Ag system, the Gd-2411-W (Gd<sub>2</sub>Ba<sub>4</sub>Cu<sub>2‒</sub><i><sub>x</sub></i>W<i><sub>x</sub></i>O<sub>12‒</sub><i><sub>ẟ</sub></i>) pinning phase was selected and integrated into the superconducting matrix in 0%, 1%, 2%, 3%, 5%, 7.5%, 10%, and 13% mass concentration. While such a high concentration of pinning would negatively impact superconducting properties, it is astonishing that it did not significantly impede crystal growth. In the sample containing 3 wt.% pinning phase, a significant increase in the maximum trapped field (over 35%) was observed compared to the reference without a pinning phase. In addition, high trapped field homogeneity typical for SDMG-grown bulks was observed in all prepared samples. The obtained results show the extreme robustness of the SDMG growth and hint at enormous potential for SDMG-grown bulks containing high amounts of artificial pinning.</p>","PeriodicalId":200,"journal":{"name":"Journal of the American Ceramic Society","volume":"108 9","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jace.20678","citationCount":"0","resultStr":"{\"title\":\"Efficient integration of Gd-2411-W artificial pinning in single-direction melt-grown GdBCO/Ag bulks in high amounts\",\"authors\":\"Oskar Chmel, Ondřej Jankovský, Tomáš Hlásek, Michal Lojka, David Sedmidubský, Petra Šimonová, Filip Antončík\",\"doi\":\"10.1111/jace.20678\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>To increase the application potential of superconducting materials, their key properties, such as critical current density, trapped field, and overall homogeneity, must be improved. It is long established that these properties can be enhanced by pinning phase addition. However, the innate fragility of top-seeded melt growth has prohibited a substantial amount of pinning from being added to bulks grown by top-seeded melt growth. Due to its robustness, the newly developed single-direction melt growth (SDMG) method should allow the integration of significantly higher mass concentrations into the superconducting matrix. For the GdBCO/Ag system, the Gd-2411-W (Gd<sub>2</sub>Ba<sub>4</sub>Cu<sub>2‒</sub><i><sub>x</sub></i>W<i><sub>x</sub></i>O<sub>12‒</sub><i><sub>ẟ</sub></i>) pinning phase was selected and integrated into the superconducting matrix in 0%, 1%, 2%, 3%, 5%, 7.5%, 10%, and 13% mass concentration. While such a high concentration of pinning would negatively impact superconducting properties, it is astonishing that it did not significantly impede crystal growth. In the sample containing 3 wt.% pinning phase, a significant increase in the maximum trapped field (over 35%) was observed compared to the reference without a pinning phase. In addition, high trapped field homogeneity typical for SDMG-grown bulks was observed in all prepared samples. The obtained results show the extreme robustness of the SDMG growth and hint at enormous potential for SDMG-grown bulks containing high amounts of artificial pinning.</p>\",\"PeriodicalId\":200,\"journal\":{\"name\":\"Journal of the American Ceramic Society\",\"volume\":\"108 9\",\"pages\":\"\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-05-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jace.20678\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1111/jace.20678\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/jace.20678","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Efficient integration of Gd-2411-W artificial pinning in single-direction melt-grown GdBCO/Ag bulks in high amounts
To increase the application potential of superconducting materials, their key properties, such as critical current density, trapped field, and overall homogeneity, must be improved. It is long established that these properties can be enhanced by pinning phase addition. However, the innate fragility of top-seeded melt growth has prohibited a substantial amount of pinning from being added to bulks grown by top-seeded melt growth. Due to its robustness, the newly developed single-direction melt growth (SDMG) method should allow the integration of significantly higher mass concentrations into the superconducting matrix. For the GdBCO/Ag system, the Gd-2411-W (Gd2Ba4Cu2‒xWxO12‒ẟ) pinning phase was selected and integrated into the superconducting matrix in 0%, 1%, 2%, 3%, 5%, 7.5%, 10%, and 13% mass concentration. While such a high concentration of pinning would negatively impact superconducting properties, it is astonishing that it did not significantly impede crystal growth. In the sample containing 3 wt.% pinning phase, a significant increase in the maximum trapped field (over 35%) was observed compared to the reference without a pinning phase. In addition, high trapped field homogeneity typical for SDMG-grown bulks was observed in all prepared samples. The obtained results show the extreme robustness of the SDMG growth and hint at enormous potential for SDMG-grown bulks containing high amounts of artificial pinning.
期刊介绍:
The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials.
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