{"title":"基于碳酸氢铵的co2响应微乳液对含油污泥进行采油","authors":"Sihang Ma, Yuanyuan Wang, Qingfeng Hou, Yifeng Liu, Xiaoling Yi, Zhuoyan Zhu, Zhidong Chang","doi":"10.1002/jsde.12848","DOIUrl":null,"url":null,"abstract":"<p>In the petroleum and petrochemical industries, oil sludge is a common contaminant that causes environmental pollution and resource wastage. Currently, recovering crude oil from oily sludge presents a significant challenge during processing. In this study, an amidinium bicarbonate-based CO<sub>2</sub>-responsive microemulsion was developed to effectively treat sludge and recover crude oil. The microemulsion system demonstrates a strong capability for oil solubilization. After the microemulsion treatment, the residual oil contents in the sludge can be reduced to as low as 2.93% (ME-1, n-butanol as cosurfactant) and 1.44% (ME-2, n-hexanol as cosurfactant). Complete oil/water phase separation can be achieved by introducing N<sub>2</sub> at 65°C.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":"28 4","pages":"913-922"},"PeriodicalIF":1.6000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Oil recovery from oily sludge using amidinium bicarbonate-based CO2-responsive microemulsion\",\"authors\":\"Sihang Ma, Yuanyuan Wang, Qingfeng Hou, Yifeng Liu, Xiaoling Yi, Zhuoyan Zhu, Zhidong Chang\",\"doi\":\"10.1002/jsde.12848\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In the petroleum and petrochemical industries, oil sludge is a common contaminant that causes environmental pollution and resource wastage. Currently, recovering crude oil from oily sludge presents a significant challenge during processing. In this study, an amidinium bicarbonate-based CO<sub>2</sub>-responsive microemulsion was developed to effectively treat sludge and recover crude oil. The microemulsion system demonstrates a strong capability for oil solubilization. After the microemulsion treatment, the residual oil contents in the sludge can be reduced to as low as 2.93% (ME-1, n-butanol as cosurfactant) and 1.44% (ME-2, n-hexanol as cosurfactant). Complete oil/water phase separation can be achieved by introducing N<sub>2</sub> at 65°C.</p>\",\"PeriodicalId\":17083,\"journal\":{\"name\":\"Journal of Surfactants and Detergents\",\"volume\":\"28 4\",\"pages\":\"913-922\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2025-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Surfactants and Detergents\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12848\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surfactants and Detergents","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12848","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Oil recovery from oily sludge using amidinium bicarbonate-based CO2-responsive microemulsion
In the petroleum and petrochemical industries, oil sludge is a common contaminant that causes environmental pollution and resource wastage. Currently, recovering crude oil from oily sludge presents a significant challenge during processing. In this study, an amidinium bicarbonate-based CO2-responsive microemulsion was developed to effectively treat sludge and recover crude oil. The microemulsion system demonstrates a strong capability for oil solubilization. After the microemulsion treatment, the residual oil contents in the sludge can be reduced to as low as 2.93% (ME-1, n-butanol as cosurfactant) and 1.44% (ME-2, n-hexanol as cosurfactant). Complete oil/water phase separation can be achieved by introducing N2 at 65°C.
期刊介绍:
Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.