Ag2S/X (X: Co和Ni)纳米晶在染料敏化太阳能电池中作为对电极的性能

IF 2.4 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
Sultan Suleyman Ozel , Esen Dagasan Bulucu , Adem Sarilmaz , Faruk Ozel
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引用次数: 0

摘要

本研究采用热注入法合成了硫化银(Ag2S)基纳米晶体(NCs)。这些NCs被用作染料敏化太阳能电池(DSSCs)的对电极,这是首次使用这些NCs作为催化剂而不是铂(Pt)的一种智能方法。在相同条件下,对DSSCs技术中基于ag2的对电极(CEs)的性能与传统的基于pt的电极进行了比较分析。研究结果表明,基于ag2的DSSCs的功率转换效率(±)比基于铂的DSSCs高约5.2%。因此,本研究的结果表明,基于ag2的NCs具有作为低成本、无铂太阳能电池的新型对电极材料的潜力。此外,这项研究的结果对发展具有成本效益和可持续的太阳能解决办法具有相当大的影响。基于ag2的NCs的出现标志着寻求可持续和高效能源解决方案的重要里程碑。本研究还邀请进一步探索其他潜在的材料组合和合成方法,以提高DSSCs的性能和性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The performance of Ag2S/X (X: Co and Ni) nanocrystals as counter electrodes in dye-sensitized solar cells

The performance of Ag2S/X (X: Co and Ni) nanocrystals as counter electrodes in dye-sensitized solar cells
In the present study, Silver sulfide (Ag2S)-based nanocrystals (NCs) were synthesized by employing a facile hot injection method. These NCs are utilized as counter electrodes on dye-sensitized solar cells (DSSCs), representing a smart approach that utilizes these NCs as catalysts instead of platinum (Pt) for the first time. The study provides a comparative analysis of the performance of Ag2S-based counter electrodes (CEs) in DSSCs technologies the traditionally compared Pt-based electrodes under identical conditions. The findings showed that the Ag2S-based DSSCs exhibited a power conversion efficiency (ƞ) that was approximately 5.2 % higher than that of the platinum-based DSSCs. Consequently, the results of this study demonstrate that Ag2S-based NCs possess the potential to function as novel counter electrode materials for low-cost, Pt-free solar cells. Moreover, the results of this study bear considerable implications for the development of cost-effective and sustainable solar energy solutions. The advent of Ag2S-based NCs signifies a significant milestone in the quest for sustainable and efficient energy solutions. This study also invites further exploration into other potential material combinations and synthesis methods that could enhance the properties and performance of DSSCs.
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来源期刊
Polyhedron
Polyhedron 化学-晶体学
CiteScore
4.90
自引率
7.70%
发文量
515
审稿时长
2 months
期刊介绍: Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry. Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.
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