{"title":"金属间化合物DyCoAl的磁热特性及跨磁跃迁临界现象研究","authors":"Mily Kundu, Sourav Sarkar, Kalyan Mandal","doi":"10.1016/j.jmmm.2025.173290","DOIUrl":null,"url":null,"abstract":"<div><div>Herein we report the magnetocaloric properties, critical analysis across magnetic phase transition and investigated their correlation for the ternary intermetallic compound DyCoAl that belongs to MgZn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>-type structure with space group <em>P6</em><span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span><em>/mmc</em>. The nature of magnetic phase transition is investigated by conducting critical analysis in the vicinity of ferromagnetic-paramagnetic transition temperature (<span><math><mrow><mo>∼</mo><mn>37</mn></mrow></math></span> K) by means of modified Arrot plot, Kouvel-Fisher plot, critical isotherm, heat capacity data analysis as well as magnetocaloric study. We acquire the critical exponents <span><math><mrow><mi>α</mi><mo>∼</mo><mn>0</mn><mo>.</mo><mn>81</mn></mrow></math></span>, <span><math><mrow><mi>β</mi><mo>∼</mo><mn>0</mn><mo>.</mo><mn>20</mn></mrow></math></span>, <span><math><mrow><mi>γ</mi><mo>∼</mo><mn>0</mn><mo>.</mo><mn>77</mn></mrow></math></span>, <span><math><mrow><mi>δ</mi><mo>∼</mo><mn>4</mn><mo>.</mo><mn>8</mn></mrow></math></span>, <span><math><mrow><msub><mrow><mi>T</mi></mrow><mrow><mi>c</mi></mrow></msub><mo>∼</mo><mn>39</mn></mrow></math></span> K, validating their self-consistency and reliability through the Widom scaling law and scaling equations. The compound exhibits a very high relative cooling power (RCP) of <span><math><mrow><mo>∼</mo><mn>1319</mn></mrow></math></span> J/kg and a moderate adiabatic temperature change of <span><math><mrow><mo>∼</mo><mn>6</mn><mo>.</mo><mn>7</mn></mrow></math></span> K for a field change of 90 kOe. The mechanical efficiency of this compound is significantly larger compared to other refrigerants operating in cryogenic temperature range, positioning it as a promising candidate for various technological applications.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"629 ","pages":"Article 173290"},"PeriodicalIF":2.5000,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of magnetocaloric properties and critical phenomenon of the intermetallic compound DyCoAl across magnetic transition\",\"authors\":\"Mily Kundu, Sourav Sarkar, Kalyan Mandal\",\"doi\":\"10.1016/j.jmmm.2025.173290\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Herein we report the magnetocaloric properties, critical analysis across magnetic phase transition and investigated their correlation for the ternary intermetallic compound DyCoAl that belongs to MgZn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>-type structure with space group <em>P6</em><span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span><em>/mmc</em>. The nature of magnetic phase transition is investigated by conducting critical analysis in the vicinity of ferromagnetic-paramagnetic transition temperature (<span><math><mrow><mo>∼</mo><mn>37</mn></mrow></math></span> K) by means of modified Arrot plot, Kouvel-Fisher plot, critical isotherm, heat capacity data analysis as well as magnetocaloric study. We acquire the critical exponents <span><math><mrow><mi>α</mi><mo>∼</mo><mn>0</mn><mo>.</mo><mn>81</mn></mrow></math></span>, <span><math><mrow><mi>β</mi><mo>∼</mo><mn>0</mn><mo>.</mo><mn>20</mn></mrow></math></span>, <span><math><mrow><mi>γ</mi><mo>∼</mo><mn>0</mn><mo>.</mo><mn>77</mn></mrow></math></span>, <span><math><mrow><mi>δ</mi><mo>∼</mo><mn>4</mn><mo>.</mo><mn>8</mn></mrow></math></span>, <span><math><mrow><msub><mrow><mi>T</mi></mrow><mrow><mi>c</mi></mrow></msub><mo>∼</mo><mn>39</mn></mrow></math></span> K, validating their self-consistency and reliability through the Widom scaling law and scaling equations. The compound exhibits a very high relative cooling power (RCP) of <span><math><mrow><mo>∼</mo><mn>1319</mn></mrow></math></span> J/kg and a moderate adiabatic temperature change of <span><math><mrow><mo>∼</mo><mn>6</mn><mo>.</mo><mn>7</mn></mrow></math></span> K for a field change of 90 kOe. The mechanical efficiency of this compound is significantly larger compared to other refrigerants operating in cryogenic temperature range, positioning it as a promising candidate for various technological applications.</div></div>\",\"PeriodicalId\":366,\"journal\":{\"name\":\"Journal of Magnetism and Magnetic Materials\",\"volume\":\"629 \",\"pages\":\"Article 173290\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2025-06-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Magnetism and Magnetic Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0304885325005220\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Magnetism and Magnetic Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304885325005220","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Investigation of magnetocaloric properties and critical phenomenon of the intermetallic compound DyCoAl across magnetic transition
Herein we report the magnetocaloric properties, critical analysis across magnetic phase transition and investigated their correlation for the ternary intermetallic compound DyCoAl that belongs to MgZn-type structure with space group P6/mmc. The nature of magnetic phase transition is investigated by conducting critical analysis in the vicinity of ferromagnetic-paramagnetic transition temperature ( K) by means of modified Arrot plot, Kouvel-Fisher plot, critical isotherm, heat capacity data analysis as well as magnetocaloric study. We acquire the critical exponents , , , , K, validating their self-consistency and reliability through the Widom scaling law and scaling equations. The compound exhibits a very high relative cooling power (RCP) of J/kg and a moderate adiabatic temperature change of K for a field change of 90 kOe. The mechanical efficiency of this compound is significantly larger compared to other refrigerants operating in cryogenic temperature range, positioning it as a promising candidate for various technological applications.
期刊介绍:
The Journal of Magnetism and Magnetic Materials provides an important forum for the disclosure and discussion of original contributions covering the whole spectrum of topics, from basic magnetism to the technology and applications of magnetic materials. The journal encourages greater interaction between the basic and applied sub-disciplines of magnetism with comprehensive review articles, in addition to full-length contributions. In addition, other categories of contributions are welcome, including Critical Focused issues, Current Perspectives and Outreach to the General Public.
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Technically original research documents that report results of value to the communities that comprise the journal audience. The link between chemical, structural and microstructural properties on the one hand and magnetic properties on the other hand are encouraged.
In addition to general topics covering all areas of magnetism and magnetic materials, the full-length articles also include three sub-sections, focusing on Nanomagnetism, Spintronics and Applications.
The sub-section on Nanomagnetism contains articles on magnetic nanoparticles, nanowires, thin films, 2D materials and other nanoscale magnetic materials and their applications.
The sub-section on Spintronics contains articles on magnetoresistance, magnetoimpedance, magneto-optical phenomena, Micro-Electro-Mechanical Systems (MEMS), and other topics related to spin current control and magneto-transport phenomena. The sub-section on Applications display papers that focus on applications of magnetic materials. The applications need to show a connection to magnetism.
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Review articles organize, clarify, and summarize existing major works in the areas covered by the Journal and provide comprehensive citations to the full spectrum of relevant literature.