金属间化合物DyCoAl的磁热特性及跨磁跃迁临界现象研究

IF 2.5 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Mily Kundu, Sourav Sarkar, Kalyan Mandal
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引用次数: 0

摘要

本文报道了空间群为P63/mmc的mgzn2型三元金属间化合物DyCoAl的磁热学性质、磁相变临界分析及其相关性。通过改进的Arrot图、Kouvel-Fisher图、临界等温线、热容数据分析以及磁热学研究,在铁磁-顺磁转变温度(~ 37 K)附近进行了临界分析,研究了磁相变的性质。我们获得了临界指数α ~ 0.81, β ~ 0.20, γ ~ 0.77, δ ~ 4.8, Tc ~ 39k,并通过Widom标度定律和标度方程验证了它们的自一致性和可靠性。该化合物表现出极高的相对冷却功率(RCP),为~ 1319 J/kg,在90 kOe的场变化下,其绝热温度变化适中,为~ 6.7 K。与其他在低温范围内工作的制冷剂相比,该化合物的机械效率显著提高,使其成为各种技术应用的有前途的候选者。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of magnetocaloric properties and critical phenomenon of the intermetallic compound DyCoAl across magnetic transition
Herein we report the magnetocaloric properties, critical analysis across magnetic phase transition and investigated their correlation for the ternary intermetallic compound DyCoAl that belongs to MgZn2-type structure with space group P63/mmc. The nature of magnetic phase transition is investigated by conducting critical analysis in the vicinity of ferromagnetic-paramagnetic transition temperature (37 K) by means of modified Arrot plot, Kouvel-Fisher plot, critical isotherm, heat capacity data analysis as well as magnetocaloric study. We acquire the critical exponents α0.81, β0.20, γ0.77, δ4.8, Tc39 K, validating their self-consistency and reliability through the Widom scaling law and scaling equations. The compound exhibits a very high relative cooling power (RCP) of 1319 J/kg and a moderate adiabatic temperature change of 6.7 K for a field change of 90 kOe. The mechanical efficiency of this compound is significantly larger compared to other refrigerants operating in cryogenic temperature range, positioning it as a promising candidate for various technological applications.
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来源期刊
Journal of Magnetism and Magnetic Materials
Journal of Magnetism and Magnetic Materials 物理-材料科学:综合
CiteScore
5.30
自引率
11.10%
发文量
1149
审稿时长
59 days
期刊介绍: The Journal of Magnetism and Magnetic Materials provides an important forum for the disclosure and discussion of original contributions covering the whole spectrum of topics, from basic magnetism to the technology and applications of magnetic materials. The journal encourages greater interaction between the basic and applied sub-disciplines of magnetism with comprehensive review articles, in addition to full-length contributions. In addition, other categories of contributions are welcome, including Critical Focused issues, Current Perspectives and Outreach to the General Public. Main Categories: Full-length articles: Technically original research documents that report results of value to the communities that comprise the journal audience. The link between chemical, structural and microstructural properties on the one hand and magnetic properties on the other hand are encouraged. In addition to general topics covering all areas of magnetism and magnetic materials, the full-length articles also include three sub-sections, focusing on Nanomagnetism, Spintronics and Applications. The sub-section on Nanomagnetism contains articles on magnetic nanoparticles, nanowires, thin films, 2D materials and other nanoscale magnetic materials and their applications. The sub-section on Spintronics contains articles on magnetoresistance, magnetoimpedance, magneto-optical phenomena, Micro-Electro-Mechanical Systems (MEMS), and other topics related to spin current control and magneto-transport phenomena. The sub-section on Applications display papers that focus on applications of magnetic materials. The applications need to show a connection to magnetism. Review articles: Review articles organize, clarify, and summarize existing major works in the areas covered by the Journal and provide comprehensive citations to the full spectrum of relevant literature.
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