三氟甲基亚硝基合成n -三氟甲基亚亚胺及其合成潜力

IF 4.7 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2025-06-25 DOI:10.1039/d5qo00873e

Norbert Baris, Martin Dracinsky, Luca Julianna Tóth, Blanka Klepetarova, Petr Beier

引用次数: 0

摘要

将叠氮三氟甲烷加入到硫化物中，光催化生成新的n -三氟甲基亚胺。它们的甲基化生成n -甲基- n三氟甲基磺酸盐，氧化生成n -三氟甲基亚砜胺。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis of N-Trifluoromethylsulfilimines via Trifluoromethyl Nitrene and Their Synthetic Potential

Trifluoromethyl nitrene generated photocatalytically from azidotrifluoromethane added to sulfides to afford new N-trifluoromethylsulfilimines. Their methylation yielded N-methyl-N trifluoromethyl sulfonium salts and oxidation provided N-trifluoromethyl sulfoximines.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.