Jorge Crespo, Carolina Muñoz-Saez, Simon M. Jowitt, Randal Burns
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However, the criticality of the REEs and the poorly known nature of their mineralization within these lithium systems the evaluation of their potential recovery as by-products of Li extraction. This study investigates the occurrence of REE-bearing minerals within the Li clays at Thacker Pass. Statistical analysis of a drill core geochemical inductively coupled plasma-mass spectrometry (ICP-MS) database shows a strong correlation between Ce and La (r = 0.9). Scanning electron microscopy observations confirmed the presence of bastnäsite, synchysite, and monazite as micrometer-sized grains within Li-rich smectite and illite mineralized zones. Semiquantitative analyses identified Ce, La, Nd, and Pr as major components of these minerals. Despite the low individual REE concentrations (Ce <300 ppm, La <150 ppm) of bulk samples from Thacker Pass, the presence of the REEs as discrete minerals suggests they could potentially be recovered as by-products of Li extraction. 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引用次数: 0
摘要
锂(Li)和稀土元素(ree)是现代技术和能源转型的关键矿物,因为它们在能源储存、运输和低二氧化碳发电方面发挥着重要作用,而且它们的供应链本身就不安全。内华达州和俄勒冈州的麦克德米特火山口拥有重要的锂资源,包括内华达州的Thacker Pass矿床,这是全球已知最大的锂资源之一,矿产资源估计为6610万吨碳酸锂当量(LCE),以及俄勒冈州的麦克德米特矿床(含21.5亿吨LCE)。虽然这些矿床在勘探过程中发现了一定数量的稀土元素,但这些关键商品并不是本区李粘土勘探的主要目标。然而,稀土元素的临界性和它们在这些锂系统中的矿化性质尚不清楚,因此很难评估它们作为锂萃取副产物的潜在回收率。本文研究了萨克山口黎系粘土中含稀土矿物的赋存状态。对岩心地球化学电感耦合等离子体质谱(ICP-MS)数据库的统计分析表明,Ce和La之间存在较强的相关性(r = 0.9)。扫描电镜观察证实,在富锂蒙脱石和伊利石矿化带中,存在bastnäsite、合土石和独居石等微米级颗粒。半定量分析确定Ce、La、Nd和Pr是这些矿物的主要成分。尽管Thacker Pass大量样品的单个REE浓度较低(Ce <300 ppm, La <150 ppm),但REE作为离散矿物的存在表明它们可能作为Li提取的副产物被回收。这是对锂粘土矿床稀土元素潜力的首次评估,强调了对内华达州和全球类似矿床进行进一步评估的必要性。这些发现强调了从锂粘土资源中回收稀土元素的潜在重要性,有助于实现更多样化和安全的供应链,并支持全球能源转型。
RARE EARTH MINERALS IN LITHIUM CLAY DEPOSITS: INSIGHTS FROM THE THACKER PASS DEPOSIT, NORTHERN NEVADA, USA
Lithium (Li) and the rare earth elements (REEs) are critical minerals for modern technologies and the energy transition due to their roles in energy storage, transport, and low-CO2 power generation and their inherently insecure supply chains. The McDermitt caldera in Nevada and Oregon hosts significant lithium resources, including the Thacker Pass deposit in Nevada—one of the largest known Li resources globally, with a mineral resource estimate of 66.1 million tonnes (Mt) of contained lithium carbonate equivalent (LCE)—as well as the McDermitt deposit in Oregon (215 Mt contained LCE). Although these deposits are known to contain some amount of the REEs as identified during exploration, these critical commodities were not the primary target during the Li clay exploration in this area. However, the criticality of the REEs and the poorly known nature of their mineralization within these lithium systems the evaluation of their potential recovery as by-products of Li extraction. This study investigates the occurrence of REE-bearing minerals within the Li clays at Thacker Pass. Statistical analysis of a drill core geochemical inductively coupled plasma-mass spectrometry (ICP-MS) database shows a strong correlation between Ce and La (r = 0.9). Scanning electron microscopy observations confirmed the presence of bastnäsite, synchysite, and monazite as micrometer-sized grains within Li-rich smectite and illite mineralized zones. Semiquantitative analyses identified Ce, La, Nd, and Pr as major components of these minerals. Despite the low individual REE concentrations (Ce <300 ppm, La <150 ppm) of bulk samples from Thacker Pass, the presence of the REEs as discrete minerals suggests they could potentially be recovered as by-products of Li extraction. This is the first assessment of the REE potential of Li clay deposits, highlighting the need for further evaluation of similar deposits in Nevada and globally. These findings emphasize the potential importance of REE recovery from Li clay resources, contributing to more diverse and secure supply chains and supporting the global energy transition.
期刊介绍:
The journal, now published semi-quarterly, was first published in 1905 by the Economic Geology Publishing Company (PUBCO), a not-for-profit company established for the purpose of publishing a periodical devoted to economic geology. On the founding of SEG in 1920, a cooperative arrangement between PUBCO and SEG made the journal the official organ of the Society, and PUBCO agreed to carry the Society''s name on the front cover under the heading "Bulletin of the Society of Economic Geologists". PUBCO and SEG continued to operate as cooperating but separate entities until 2001, when the Board of Directors of PUBCO and the Council of SEG, by unanimous consent, approved a formal agreement of merger. The former activities of the PUBCO Board of Directors are now carried out by a Publications Board, a new self-governing unit within SEG.