硫/硒原子掺入杂[7]螺旋烯用于低温圆偏振磷光

IF 4.7 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2025-06-18 DOI:10.1039/d5qo00790a

Shuai Qiu, Yuexia Dong, Wan Xu, Sheng Zhang, Chunli Li, Hua Wang

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引用次数: 0

摘要

通过分子间McMurry反应和氧化光环反应，合成了3个新的噻吩/硒基S/Se-[7]螺旋烯。通过单晶分析证实了它们的螺旋结构。此外，这些[7]螺旋蛋白在77 K时表现出明显的圆极化磷光。理论计算表明，重原子效应增加了系统间的交叉通道和自旋轨道耦合常数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Sulfur/selenium atom-incorporated hetero[7]helicenes for low-temperature circularly polarized phosphorescence

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Sulfur/selenium atom-incorporated hetero[7]helicenes for low-temperature circularly polarized phosphorescence

Three new thiophene/selenophene-based S/Se-[7]helicenes were efficiently synthesized via intermolecular McMurry and oxidative photocyclization reactions. Their helical structures were confirmed through single-crystal analysis. Additionally, these [7]helicenes exhibited notable circularly polarized phosphorescence at 77 K. Theoretical calculations show that both intersystem crossing channels and spin–orbit coupling constants are increased due to the heavy atom effect.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.