锌离子电池用moo3基阴极:最新进展、挑战和未来方向

IF 5.5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Diyu Xu, Siyu Cai*, Yi Wang, Zujin Yang* and Xihong Lu*, 
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引用次数: 0

摘要

对可持续和高效能源存储解决方案的需求不断增长,激发了人们对锌离子电池(zib)作为锂基技术的可行替代品的极大兴趣,因为锌离子电池具有成本效益、更高的安全性和环境兼容性。三氧化钼(MoO3)由于其独特的层状结构、较高的理论容量和适应性强的电子性能而受到了广泛的关注。然而,MoO3阴极的实际应用受到诸如低电子导电性、结构不稳定和溶于水电解质等挑战的阻碍。本文综述了ZIBs中MoO3阴极的最新进展,重点介绍了结构调节、价态调制、嵌入工程和电解质优化等策略。此外,该综述概述了未来的研究方向,旨在释放MoO3阴极的全部潜力,从而促进其在下一代储能系统中的商业化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

MoO3-Based Cathodes for Zinc-Ion Batteries: Recent Advances, Challenges, and Future Directions

MoO3-Based Cathodes for Zinc-Ion Batteries: Recent Advances, Challenges, and Future Directions

The increasing demand for sustainable and efficient energy storage solutions has spurred significant interest in zinc-ion batteries (ZIBs) as viable alternatives to lithium-based technologies, driven by their cost-effectiveness, enhanced safety, and environmental compatibility. Among the diverse cathode materials investigated for ZIBs, molybdenum trioxide (MoO3) has garnered considerable attention due to its distinctive layered structure, high theoretical capacity, and adaptable electronic properties. Nevertheless, practical applications of MoO3 cathodes are impeded by challenges such as low electronic conductivity, structural instability, and dissolution in aqueous electrolytes. This Review offers a comprehensive examination of recent advancements in MoO3 cathodes for ZIBs, emphasizing strategies including structural regulation, valence modulation, intercalation engineering and electrolyte optimization. Furthermore, the Review outlines future research directions aimed at unlocking the full potential of MoO3 cathodes, thereby facilitating their commercialization in next-generation energy storage systems.

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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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