{"title":"Fe-SiOC柱状纳米复合材料尺寸相关的各向异性变形行为","authors":"Jian Song, Bingqiang Wei, Jian Wang","doi":"10.1016/j.scriptamat.2025.116833","DOIUrl":null,"url":null,"abstract":"<div><div>Fe-SiOC nanocomposites with core-shell (crystal-amorphous) columnar structures exhibit size dependent, anisotropic mechanical properties. When loading along the columns, the yield strength of Fe-SiOC increases from 2.6 GPa to 3.5 GPa as the column diameter decreases from ∼14.0 nm to ∼3.7 nm. In contrast, the yield strength of Fe-SiOC decreases from 3.1 GPa to 2.5 GPa when the loading is perpendicular to the columns. Combining with transmission electron microscope (TEM) analysis, the anisotropic mechanical properties were attributed to the size-dependent transition of deformation mechanisms from co-deformation (Fe and SiOC) to grain boundaries mediated cracking.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"267 ","pages":"Article 116833"},"PeriodicalIF":5.3000,"publicationDate":"2025-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Size dependent, anisotropic deformation behaviors of Fe-SiOC columnar nanocomposites\",\"authors\":\"Jian Song, Bingqiang Wei, Jian Wang\",\"doi\":\"10.1016/j.scriptamat.2025.116833\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Fe-SiOC nanocomposites with core-shell (crystal-amorphous) columnar structures exhibit size dependent, anisotropic mechanical properties. When loading along the columns, the yield strength of Fe-SiOC increases from 2.6 GPa to 3.5 GPa as the column diameter decreases from ∼14.0 nm to ∼3.7 nm. In contrast, the yield strength of Fe-SiOC decreases from 3.1 GPa to 2.5 GPa when the loading is perpendicular to the columns. Combining with transmission electron microscope (TEM) analysis, the anisotropic mechanical properties were attributed to the size-dependent transition of deformation mechanisms from co-deformation (Fe and SiOC) to grain boundaries mediated cracking.</div></div>\",\"PeriodicalId\":423,\"journal\":{\"name\":\"Scripta Materialia\",\"volume\":\"267 \",\"pages\":\"Article 116833\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2025-06-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scripta Materialia\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1359646225002969\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646225002969","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Size dependent, anisotropic deformation behaviors of Fe-SiOC columnar nanocomposites
Fe-SiOC nanocomposites with core-shell (crystal-amorphous) columnar structures exhibit size dependent, anisotropic mechanical properties. When loading along the columns, the yield strength of Fe-SiOC increases from 2.6 GPa to 3.5 GPa as the column diameter decreases from ∼14.0 nm to ∼3.7 nm. In contrast, the yield strength of Fe-SiOC decreases from 3.1 GPa to 2.5 GPa when the loading is perpendicular to the columns. Combining with transmission electron microscope (TEM) analysis, the anisotropic mechanical properties were attributed to the size-dependent transition of deformation mechanisms from co-deformation (Fe and SiOC) to grain boundaries mediated cracking.
期刊介绍:
Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.